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無電解PdめっきによるZrおよびZr3Al2ゲッターの表面改質
https://doi.org/10.15099/00006393
https://doi.org/10.15099/00006393aced4530-9517-4ae3-b816-48df62428485
名前 / ファイル | ライセンス | アクション |
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2007-10-03 | |||||
タイトル | ||||||
タイトル | 無電解PdめっきによるZrおよびZr3Al2ゲッターの表面改質 | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.15099/00006393 | |||||
ID登録タイプ | JaLC | |||||
著者 |
芦田, 完
× 芦田, 完× 渡辺, 国昭× 諸住, 正太郎× 松田, 健二× 多々, 静夫× Ashida, Kan |
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著者別名 | ||||||
姓名 | Watanabe, Kuniaki | |||||
著者別名 | ||||||
姓名 | Morozumi, Shotaro | |||||
著者別名 | ||||||
姓名 | Matsuda, Kenji | |||||
著者別名 | ||||||
姓名 | Tada, Shizuo | |||||
その他(別言語等)のタイトル | ||||||
その他のタイトル | Surface Modification of Zr and Zr_3Al_2 with Electroless Pd Plati | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Hydrogen storage materials lose their effectiveness in the presence of small amounts of impurity gases in hydrogen owing to the formation of oxide and/or carbide layers on the surface of materials. To avoid this impairment, applicability of Pd coating as protective layer was examined. Zr and Zr3Al2 were selected as model substrates and coated with Pd with electroless plating method. The characteristics of the Pd coating were examined with scanning electron microscopy (SEM), electron probe microanalysis (EPMA), x-ray photoelectron spectroscopy (XPS) and thermal desorption spectroscopy (TDS). SEM observations showed that dense and relatively smooth Pd-overlayers could be prepared with this method on combination with vacuum annealing. EPMA and XPS revealed that mutual diffusion of the relevant elements took place above 600℃. As a consequence, the elements of the substrates on the surface. Zr, however, was present as ZrC, whereas, Pd was kept in its pure metallic state. TDS showed that Zr played no important role in absorption and desorption of deuterium and only the Pd-overlayer took part in the ab/desorption processes, indicating that the Pd layer acts as permeation window for hydrogen and can protect the inner substrate from impurity gases. | |||||
書誌情報 |
富山大学水素同位体機能研究センター研究報告 巻 12, p. 59-69, 発行日 1992 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0916-8486 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN10443060 | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 | ||||||
出版者 | 富山大学水素同位体機能研究センター | |||||
資源タイプ(DSpace) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article |