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アルミニウム粒と四塩化炭素との反応のジイソプロピルサリチル酸塩添加による阻害作用ならびに溶媒効果
https://doi.org/10.15099/00003917
https://doi.org/10.15099/000039176cad05e0-b6aa-4271-a935-50533d0f7e2a
名前 / ファイル | ライセンス | アクション |
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Kokiyo_16_01_Page092to096.pdf (1.6 MB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2012-09-21 | |||||
タイトル | ||||||
タイトル | アルミニウム粒と四塩化炭素との反応のジイソプロピルサリチル酸塩添加による阻害作用ならびに溶媒効果 | |||||
言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | アルミニウム粒と四塩化炭素との反応 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | アルミニウム粒 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 四塩化炭素 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | ジイソプロピルサリチル酸塩添加 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 阻害作用 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 溶媒効果 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 有機溶媒 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 反応誘導期 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Dips塩類 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | ジメチルホルムアミド溶液 | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.15099/00003917 | |||||
ID登録タイプ | JaLC | |||||
著者 |
浅岡, 忠知
× 浅岡, 忠知× 作道, 栄一× 島崎, 長一郎× 三好, 勉× 安本, 弘 |
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著者別名 | ||||||
姓名 | ASAOKA, Tadatomo | |||||
著者別名 | ||||||
姓名 | TSUKURIMITI, Eiiti | |||||
著者別名 | ||||||
姓名 | SIMASAKI, Choichiro | |||||
著者別名 | ||||||
姓名 | MIYOSI, Tutomu | |||||
著者別名 | ||||||
姓名 | YASUMOTO, Hirosi | |||||
その他(別言語等)のタイトル | ||||||
その他のタイトル | Retarding Action of Various Metallic Diisopropyl Salicylate on the Reaction between Aluminum Particles and Carbon Tetrachloride, and Solvent Effects for this Reaction | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Retarding action of many sorts of inhibitors on the reaction between aluminum particles and carbon tetrachloride was reported in the previous many papers. Now the similar studies using various metallic diisopropyl salicylate which may ionize in the organic solvent are carried out, and further-more solvent effects of ligroin, decalin, tetralin and methylcyclohexane are checked. The outline of results may be summarized in the following: (1) Various metallic diisopropyl salicylate having ionizing ability in the organic solvent prolonged the induction period, and some relation between the critical concentration of the induction period and the specific conductivity was showed this reaction, therefore, was presumed appreciably different from the radical reaction suggested by M.Stern. (2) In solvent effects of three solvents excepting tetralin, the induction period is shortened with a narrow range having the small quantity, but is prolonged with the quantity beyond that range. (3) The order of prolonged induction period with mixed inhibitors in these solvents may be classified into two groups, that is, the order of methylclohexane is normal, whereas the order of ligroin or decaline is inverse. It seems that this order associated the adaptability of Al ion concentration from AlCl_3 complex of respective stability. |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | アルミニウム粒と四塩化炭素との反応について,各種の阻害剤の添加効果に対する研究を従来浅間らが多数の報告を行って来ている。 本報ではこれらに関連して,有機溶媒中で電離性のあるジイソプロピルサリチル酸の各種金属塩類(以下本稿中ではDips塩類と略記する)の添加による阻害作用と溶媒としてリグロイン,デカリン,メチルシクロヘキサン,テトラリンを添加した場合の反応誘導期におよぼす影響について行ったものである。 |
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引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 富山大学工学部紀要,16(1/2) | |||||
書誌情報 |
富山大学工学部紀要 巻 16, 号 1/2, p. 92-96, 発行日 1965-03 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 03871339 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00175872 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
国立国会図書館分類 | ||||||
主題Scheme | NDLC | |||||
主題 | ZM2 | |||||
出版者 | ||||||
出版者 | 富山大学工学部 | |||||
資源タイプ(DSpace) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article |