@article{oai:toyama.repo.nii.ac.jp:00006551, author = {奥島, 康正 and 井上, 光浩 and 阿部, 孝之}, journal = {富山大学水素同位体科学研究センター研究報告}, month = {May}, note = {application/pdf, Degradation of a carbon-supported Pt (Pt/C) catalyst used at the cathode of polymer electrolyte fuel cells was investigated. The Pt/C sample was prepared by the polygonal barrel-sputtering method. The results showed that the Pt nanoparticles were highly dispersed on the powder carbon support. The cyclic voltammograms of the prepared Pt/C sample showed that the Pt particles were electrochemically cleaned by 100 repetitions of the potential cycling. Further continuation of potential cycling, however, resulted in the gradual decrease in H adsorption/desorption currents, indicating a loss of the electrochemical surface area (ESA) of the deposited Pt. Note that the ESA obtained after the 4000th potential cycling was ca. 20% of that at 1st potential cycling, and the decrease in the ESA is most likely attributed to the growth and aggregation of the deposited Pt particles., Article, 富山大学水素同位体科学研究センター研究報告, 32巻, 2013.05.31, pp.21-26}, pages = {21--26}, title = {多角バレルスパッタリング法を用いた固体高分子形燃料電池用カソード触媒の劣化現象評価}, volume = {32}, year = {2013} }