@article{oai:toyama.repo.nii.ac.jp:00006464,
 author = {芦田, 完 and 波多野, 雄治 and 渡辺, 国昭},
 journal = {富山大学水素同位体科学研究センター研究報告 = Annual Report of Hydrogen Isotope Research Center, Toyama University},
 month = {},
 note = {application/pdf, Kinetic analyses were performed for solid-state reactions between a hydrogen-containing carbon film and substrate metals to form metallic carbide of Me2C (Me=Be, Mo, W). Isothermal and non-isothermal reaction curves could be explained by a random nucleation and two-dimentional crystal growth model. The kinetic equation can be approximated well by -ln(1-x)= kappt2, where x is the extent of reaction and kapp the apparent rate constant. The temperature dependence of the rate constants are given as  kapp(Be)=3.10 exp(-109.[kJ/mol]/RT) [1/sec2],   kapp(Mo)=231. exp(-161.[kJ/mol]/RT),   kapp(W) =516. exp(-183.[kJ/mol]/RT),   for Be-C, Mo-C and W-C systems, respectively, where the apparent activation energy is considered to be the sum of those for nucleation and diffusion. Linear relations were found between the apparent activation energy and the melting point of substrate metals as well as the bond strength of Me-C (Me=Be, Mo, W)., Article, 富山大学水素同位体科学研究センター研究報告 = Annual Report of Hydrogen Isotope Research Center, Toyama University 20, 43-52.(2000)},
 pages = {43--52},
 title = {含水素炭素膜と金属基盤(Be, Mo, W)との反応動力学の解析},
 volume = {20},
 year = {2000}
}