@article{oai:toyama.repo.nii.ac.jp:00006450,
 author = {安松, 拓洋 and 松山, 政夫 and 渡辺, 国昭},
 journal = {富山大学水素同位体機能研究センター研究報告},
 month = {},
 note = {application/pdf, To obtain better working materials for recently developed gas chromatography for hydrogen isotope separation, pressure-composition-temperature relationships of hydrogen isotopes were examined for Pd-Pt and Pd-Ni alloys from 273K to 1073K at concentrations from 2x10-4 to 0.65 in [H]/[M] ratio. The heat of hydride formation for the alloys decreased with increasing Pt or Ni content. The isotope effect defined as the equilibrium pressure ratio, PD2/PH2, did not change much with alloy composition. The equilibrium constant at infinite dilution showed strong temperature and isotope dependence. Analysis indicated the ground state of D to be 1/√2 less than that of H for respective alloys. The thermodynamic properties of hydride phase were evaluated for all the alloys and hydrogen isotopes including tritium., Article},
 pages = {81--94},
 title = {Pd－Pt及びPd-Ni合金中における水素同位体の熱力学特性},
 volume = {18},
 year = {1998}
}