{"created":"2023-07-25T09:07:57.969828+00:00","id":6432,"links":{},"metadata":{"_buckets":{"deposit":"23802413-5af2-48cc-9ea7-ebd0b6225f27"},"_deposit":{"created_by":3,"id":"6432","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"6432"},"status":"published"},"_oai":{"id":"oai:toyama.repo.nii.ac.jp:00006432","sets":["663:777:778:789:795"]},"author_link":["59595","59603","59597","59605","59598","59606","59604","59599","21973","59600","59602"],"item_3_alternative_title_19":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Isotope effect on Disproportionation of ZrCo"}]},"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1996","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"79","bibliographicPageStart":"69","bibliographicVolumeNumber":"16","bibliographic_titles":[{"bibliographic_title":"富山大学水素同位体機能研究センター研究報告"}]}]},"item_3_description_15":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"To understand hydrogen induced disproportionation of ZrCo, the kinetics and isotope effect were studied in isothermal and in heating-cooling cycle modes. Crystallographic change owing to the disproportionation was also examined with powder X-ray diffraction. The rate of disproportionation increased with a temperature up to 873K, but decreased at high temperatures. Similar temperature dependence was observed in the heating-cooling mode. The kinetics was analyzed following the method of Sharp et al. The analyses indicated that the reaction mechanism changed from R2 to F1 around 823K. The Arrhenius plots of the disproportionation rate gave activation energies of 154 and 159 kJ/mol for hydrogen and deuterium, respectively, and the frequency factor as 1.07 and 1.34x1010/s below 823K. However, the plots showed a negative activation energy for both hydrogens in the high temperature region, where a larger activation energy was suggested for deuterium than for Those characteristics were discussed by assuming the presence of an intermediate between the reaction and product.","subitem_description_type":"Abstract"}]},"item_3_description_40":{"attribute_name":"資源タイプ(DSpace)","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_3_description_6":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"富山大学水素同位体機能研究センター研究報告 16, 69-79.(1996)","subitem_description_type":"Other"}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"59606","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Watanabe, Kuniaki"}]},{"nameIdentifiers":[{"nameIdentifier":"21973","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"9000002318184","nameIdentifierScheme":"CiNii ID","nameIdentifierURI":"http://ci.nii.ac.jp/nrid/9000002318184"},{"nameIdentifier":"00334714","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://nrid.nii.ac.jp/nrid/1000000334714"}],"names":[{"name":"Hara, Masanori"}]},{"nameIdentifiers":[{"nameIdentifier":"59602","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Kobayashi, Takahiro"}]},{"nameIdentifiers":[{"nameIdentifier":"59603","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Kobayashi, Koji"}]},{"nameIdentifiers":[{"nameIdentifier":"59604","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Okabe, Toshio"}]},{"nameIdentifiers":[{"nameIdentifier":"59605","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Mori, Katsunori"}]}]},"item_3_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.15099/00006426","subitem_identifier_reg_type":"JaLC"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"富山大学水素同位体機能研究センター"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN10443060","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0916-8486","subitem_source_identifier_type":"ISSN"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"渡辺, 国昭"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"原, 正憲"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"小林, 孝広"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"小林, 幸司"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"岡部, 俊夫"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"森, 克徳"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-17"}],"displaytype":"detail","filename":"annual_report16-6.pdf","filesize":[{"value":"428.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"annual_report16-6.pdf","url":"https://toyama.repo.nii.ac.jp/record/6432/files/annual_report16-6.pdf"},"version_id":"dbc6ba3a-4e68-4a4b-8452-0d446a46efff"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"ZrCoの不均化における同位体効果","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ZrCoの不均化における同位体効果"}]},"item_type_id":"3","owner":"3","path":["795"],"pubdate":{"attribute_name":"公開日","attribute_value":"2007-10-03"},"publish_date":"2007-10-03","publish_status":"0","recid":"6432","relation_version_is_last":true,"title":["ZrCoの不均化における同位体効果"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-07-25T14:16:40.804972+00:00"}