{"created":"2023-07-25T09:07:55.453537+00:00","id":6374,"links":{},"metadata":{"_buckets":{"deposit":"eb1120ac-499b-4328-899a-cb89cee7727b"},"_deposit":{"created_by":3,"id":"6374","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"6374"},"status":"published"},"_oai":{"id":"oai:toyama.repo.nii.ac.jp:00006374","sets":["663:777:778:779:787"]},"author_link":["21725","21726","21729","21723","21727","21730","21724","21728"],"item_3_alternative_title_19":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"赤外スペクトルによる[Co(en-d 4)_3]Cl_3・3T_2Oのβ放射線分解の研究"}]},"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1988","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"91","bibliographicPageStart":"87","bibliographicVolumeNumber":"8","bibliographic_titles":[{"bibliographic_title":"富山大学トリチウム科学センター研究報告 = Annual Report of Tritium Research Center, Toyama University"}]}]},"item_3_description_15":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"β-Radiolysis of [Co(en-d4)3]Cl3・3T2O was studied under a mild condition by means of infrared spectroscopy over a period of 8 months. The spectra became complex due to the appearance of many new bands in the initial process. This is explained in terms of the exchange reaction in hydrogen isotopes between water and ethylenediamine. It was found that ethylenediamine decomposed by ～50% in 100 days, forming ammonia coordinated to a Co2+ ion and an ammonium ion. On the other hand, a Co (Ⅲ) ammine complex, acetylene and so on were not found. A scheme for the β-radiolysis is proposed.","subitem_description_type":"Abstract"}]},"item_3_description_40":{"attribute_name":"資源タイプ(DSpace)","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"21727","nameIdentifierScheme":"WEKO"}],"names":[{"name":"金坂, 績"}]},{"nameIdentifiers":[{"nameIdentifier":"21728","nameIdentifierScheme":"WEKO"}],"names":[{"name":"西村, 裕幸"}]},{"nameIdentifiers":[{"nameIdentifier":"21729","nameIdentifierScheme":"WEKO"}],"names":[{"name":"金森, 寛"}]},{"nameIdentifiers":[{"nameIdentifier":"21730","nameIdentifierScheme":"WEKO"}],"names":[{"name":"川井, 清保"}]}]},"item_3_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.15099/00006368","subitem_identifier_reg_type":"JaLC"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"富山大学トリチウム科学センター"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN10100133","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0287-1408","subitem_source_identifier_type":"ISSN"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kanesaka, Isao"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nishimura, Hiroyuki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kanamori, Kan"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kawai, Kiyoyasu"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-17"}],"displaytype":"detail","filename":"annual_report8-8.pdf","filesize":[{"value":"377.5 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"annual_report8-8.pdf","url":"https://toyama.repo.nii.ac.jp/record/6374/files/annual_report8-8.pdf"},"version_id":"0b0079fe-2947-4b87-9447-44c5ef4192c7"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Infrared Study on β-Radiolysis of [Co(en-d 4) 3]Cl 3・3T2O (en:ethylenediamine)","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Infrared Study on β-Radiolysis of [Co(en-d 4) 3]Cl 3・3T2O (en:ethylenediamine)"}]},"item_type_id":"3","owner":"3","path":["787"],"pubdate":{"attribute_name":"公開日","attribute_value":"2007-10-03"},"publish_date":"2007-10-03","publish_status":"0","recid":"6374","relation_version_is_last":true,"title":["Infrared Study on β-Radiolysis of [Co(en-d 4) 3]Cl 3・3T2O (en:ethylenediamine)"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-07-25T15:45:05.825848+00:00"}