{"created":"2023-07-25T09:06:14.635273+00:00","id":4462,"links":{},"metadata":{"_buckets":{"deposit":"db8e111d-ba17-47fd-9740-c0c359018917"},"_deposit":{"created_by":3,"id":"4462","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"4462"},"status":"published"},"_oai":{"id":"oai:toyama.repo.nii.ac.jp:00004462","sets":["496:556:559:560:604"]},"author_link":["57562","57565","57564","57563","57568","57566","57567","57569"],"item_3_alternative_title_19":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Catalytic decomposition of formic acid in alkaline solution"}]},"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1993-03","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"79","bibliographicPageStart":"73","bibliographicVolumeNumber":"44","bibliographic_titles":[{"bibliographic_title":"富山大学工学部紀要"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"In order to obtain hydrogen as an energy source for fuel cell, the catalytic decomposition of formic acid was investigated on a platinized palladium plate in 30% KOH solution. The hydrogen once formed by the decomposition of formic acid was absorbed in platinized palladium plate by dipping method. The amount of absorbed hydrogen was increased with increasing the concentration of formic acid up to 20 vol% of formic acid and decreased above higher concentration. Voltammetric study demonstrates two kinds of adsorbed species of (A) and (B) according to the decomposition process. (A) was observed in any concentration of formic acid in alkaline solution, while (B) was not observed in dilute solution (below 20%). The properties of (A) and (B) were discussed.","subitem_description_type":"Abstract"},{"subitem_description":"水素を燃料電池用エネルギー源として使用する目的で，白金黒付きパラジウム板上30% KOH溶液中でギ酸の接触分解を行なった。\nギ酸の分解により生じた水素を白金黒付きパラジウム板に浸漬法により吸蔵させた。\n吸蔵された水素量はギ酸濃度20vol%までは増加し，それを越える濃度では減少した。\nVoltammogramの研究より，分解過程に関して(A)，(B)二種の吸着種の存在が明らかとなった。\n(A)の吸着種はアルカリ中のギ酸の全濃度範囲で観測されたが，吸着種(B)はギ酸の薄い濃度領域（20%以下）では観察されなかった。\n(A)，(B) の性質について検討した。","subitem_description_type":"Abstract"}]},"item_3_description_40":{"attribute_name":"資源タイプ(DSpace)","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_3_description_6":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"富山大学工学部紀要，44, Page 73-79","subitem_description_type":"Other"}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"57566","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Nakamura, Yuuko"}]},{"nameIdentifiers":[{"nameIdentifier":"57567","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Rengakuji, Seiichi"}]},{"nameIdentifiers":[{"nameIdentifier":"57568","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Inoue, Masami"}]},{"nameIdentifiers":[{"nameIdentifier":"57569","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Nishibe, Keiichi"}]}]},"item_3_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.15099/00004456","subitem_identifier_reg_type":"JaLC"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"富山大学工学部"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00175872","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03871339","subitem_source_identifier_type":"ISSN"}]},"item_3_subject_22":{"attribute_name":"国立国会図書館分類","attribute_value_mlt":[{"subitem_subject":"ZM2","subitem_subject_scheme":"NDLC"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"中村, 優子"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"蓮覚寺, 聖一"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"井上, 正美"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"西部, 慶一"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-16"}],"displaytype":"detail","filename":"Kokiyo_44_01_Page073to079.pdf","filesize":[{"value":"2.1 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Kokiyo_44_01_Page073to079.pdf","url":"https://toyama.repo.nii.ac.jp/record/4462/files/Kokiyo_44_01_Page073to079.pdf"},"version_id":"a96c0c2a-ca09-44e3-bd6a-5e0626b69a76"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"ギ酸の接触分解","subitem_subject_scheme":"Other"},{"subitem_subject":"燃料電池用水素極","subitem_subject_scheme":"Other"},{"subitem_subject":"接触分解反応","subitem_subject_scheme":"Other"},{"subitem_subject":"燃料電池構成材料","subitem_subject_scheme":"Other"},{"subitem_subject":"白金黒付きパラジウム","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"ギ酸の接触分解に関する研究","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ギ酸の接触分解に関する研究"}]},"item_type_id":"3","owner":"3","path":["604"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-10-12"},"publish_date":"2012-10-12","publish_status":"0","recid":"4462","relation_version_is_last":true,"title":["ギ酸の接触分解に関する研究"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-07-25T15:08:10.599076+00:00"}