@article{oai:toyama.repo.nii.ac.jp:00004006, author = {浅岡, 忠知 and 作道, 栄一 and 金子, 葵 and 小杉, 峻 and 長谷川, 洋}, issue = {1/2}, journal = {富山大学工学部紀要}, month = {Mar}, note = {As a result of our studies of this series, it has been recoginized that the procession of the reaction between benzylhalides and various metals should be closely correlating to the electro-solution voltage of each metal. Furthermore, the promoting or inhibiting action of some organic reagents for the reaction between benzyl chloride or substituted benzyl bromides and aluminum or iron was checked. Now the similar studies shown as the subtit1e is carried out. The result obtained is as follows: (i) In the self-condensation of hydroxy- or nitro-benzyl bromide with various metals, the reactivity is closely related to the electro-solution voltage of each metal and this result supports our suggestion described in the previotis reports. (ii) In the self-condensation of benzyl halides or substituted benzyl bromides with metallic sulfate, the Lewis acid function sited on the surface of solid acid followed by the action of metallic halide produced intermediately is presumed as its catalytic mechanism., 著者らはハロゲン化ベンジルと各種の金属との反応について,その進行が金属の電溶圧と密接な関連があることを見出し,さらに塩化ベンジルやオキシあるいはニトロ置換臭化ベンジルとAlまたはFeとの反応に対する有機試薬類の添加効果について検討してきているが,本報では生成ハロゲン化金属の自触作用によるハロゲン化ベンジル類の自己縮合反応の一翼として副題に掲げた研究を行なったものである。, Article, 富山大学工学部紀要,19(1/2)}, pages = {33--38}, title = {ハロゲン化炭化水素と金属類との反応性の研究(第6報) : オキシあるいはニトロ置換臭化ベンジルの各種の金属または硫酸塩による自己縮合反応ならびにハロゲン化ベンジルの各種の硫酸塩による自己縮合反応}, volume = {19}, year = {1968} }