{"created":"2023-07-25T09:05:48.882267+00:00","id":3950,"links":{},"metadata":{"_buckets":{"deposit":"b968647e-f17c-453b-ad9d-01ff3e5ef186"},"_deposit":{"created_by":3,"id":"3950","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3950"},"status":"published"},"_oai":{"id":"oai:toyama.repo.nii.ac.jp:00003950","sets":["496:556:559:560:577"]},"author_link":["55380","55383","55382","55384","55385","55378","55381","55379"],"item_3_alternative_title_19":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Effects of Various Substance on the Anhydrous Aluminum Chloride or Allied Catalyst VIII : Effects of Various metals on the Anhydrous Aluminum Chloride for the Reaction between Carbon Tetrachloride and Benzene"}]},"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1966-03","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1/2","bibliographicPageEnd":"53","bibliographicPageStart":"48","bibliographicVolumeNumber":"17","bibliographic_titles":[{"bibliographic_title":"富山大学工学部紀要"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"In the preceding paper it was shown that considerably available results had been obtained by the addition of many sorts of metals or inorganic salts to the AlCl_3 or FeCl_3 as the catalyst for the reactions, such as the ketone thynthesis, the polymerization of olefins etc. Now, from the reaction between CCl_4 and benzene with AlCl_3 tritylchloride as the sole product was obtained whereas the addition of the metals to the AlCl_3, i. e., AlCl_3-metal mixed catalyst, the mixtures of tritylchloride and tritane was produced. In this report, therefore, the reducting power of those various metals for this reaction is studied and checked also the solvent effects of some organic reagents, such as nitrobenzene, n-butylamine etc. as the additives to the mixed catalyst. The result obtained are given in following summaries. \n(1) Additive effects of 12 sorts of metals are studied for the reaction between CCl_4 and benzene with AlCl_3. \n(2) Many sorts of metals gave the positive effects in the yields and showed that the content of tritane was 20-50% ca, in the total yields due to difference in the reducing abi1ity of respective metals for the tritylchloride. \n(3) These results had some approximation to that expected from the order of the effects of various metals in the preceding reports. \n(4) The process in this reaction producing the mixtures of tritylchloride and tritane was checked as that rnight be composed of the two kinds of AlCl_3 catalytic reaction and one of them is so-called F. C reaction and the other is the reaction concerned to the tritylchloride-AlCl_3-Al complex. \n(5) The nitrobenzene added to the nixed catalyst showed the solvent effect, promoting the reaction rate, over the range of 1.5-2.5g.","subitem_description_type":"Abstract"},{"subitem_description":"無水塩化アルミニウムを触媒として四塩化炭素とベンゼンを反応させればトリフェニルクロロメタン（トリチルクロライド）が得られる。\nが，これに金属類を添加すると反応生成物の一部が還元され，トリチルクロライド（以後単にクロライドと書く）とトリフェニルメタン（トリタン）の混合物が得られる。\n本報においては各種金属とクロライド，トリタンの混合割合の関係およびアミン，アルコールなど若干の有機試薬を金属と共に添加した場合の影響を広い意味の溶媒効果として検討し，その反応操作について考察した。","subitem_description_type":"Abstract"}]},"item_3_description_40":{"attribute_name":"資源タイプ(DSpace)","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_3_description_6":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"富山大学工学部紀要，17(1/2)","subitem_description_type":"Other"}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"55382","nameIdentifierScheme":"WEKO"}],"names":[{"name":"TSUKURIMITI, Eiiti"}]},{"nameIdentifiers":[{"nameIdentifier":"55383","nameIdentifierScheme":"WEKO"}],"names":[{"name":"ASAOKA, Tadatomo"}]},{"nameIdentifiers":[{"nameIdentifier":"55384","nameIdentifierScheme":"WEKO"}],"names":[{"name":"SANO, Syuniti"}]},{"nameIdentifiers":[{"nameIdentifier":"55385","nameIdentifierScheme":"WEKO"}],"names":[{"name":"HIROKAWA, Kiyoshi"}]}]},"item_3_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.15099/00003944","subitem_identifier_reg_type":"JaLC"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"富山大学工学部"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00175872","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03871339","subitem_source_identifier_type":"ISSN"}]},"item_3_subject_22":{"attribute_name":"国立国会図書館分類","attribute_value_mlt":[{"subitem_subject":"ZM2","subitem_subject_scheme":"NDLC"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"作道, 栄一"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"浅岡, 忠知"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"佐野, 俊一"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"広川, 清"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-16"}],"displaytype":"detail","filename":"Kokiyo_17_01_Page048to053.pdf","filesize":[{"value":"5.5 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Kokiyo_17_01_Page048to053.pdf","url":"https://toyama.repo.nii.ac.jp/record/3950/files/Kokiyo_17_01_Page048to053.pdf"},"version_id":"29e3772d-aa95-4856-8438-f950a2a5ef1d"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"無水塩化アルミニウム系触媒","subitem_subject_scheme":"Other"},{"subitem_subject":"他物質添加","subitem_subject_scheme":"Other"},{"subitem_subject":"四塩化炭素とベンゼンの反応","subitem_subject_scheme":"Other"},{"subitem_subject":"金属類の添加効果","subitem_subject_scheme":"Other"},{"subitem_subject":"トリチルクロライド","subitem_subject_scheme":"Other"},{"subitem_subject":"トリフェニルメタン","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"無水塩化アルミニウム系触媒に対する他物質添加の影響の研究(第8報) : 四塩化炭素とベンゼンの反応に対する無水塩化アルミニウム触媒への金属類の添加効果","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"無水塩化アルミニウム系触媒に対する他物質添加の影響の研究(第8報) : 四塩化炭素とベンゼンの反応に対する無水塩化アルミニウム触媒への金属類の添加効果"}]},"item_type_id":"3","owner":"3","path":["577"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-09-24"},"publish_date":"2012-09-24","publish_status":"0","recid":"3950","relation_version_is_last":true,"title":["無水塩化アルミニウム系触媒に対する他物質添加の影響の研究(第8報) : 四塩化炭素とベンゼンの反応に対する無水塩化アルミニウム触媒への金属類の添加効果"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-07-25T15:13:50.100691+00:00"}