{"created":"2023-07-25T09:05:48.839217+00:00","id":3949,"links":{},"metadata":{"_buckets":{"deposit":"f56865f5-e19a-4b50-b351-c38e23250640"},"_deposit":{"created_by":3,"id":"3949","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3949"},"status":"published"},"_oai":{"id":"oai:toyama.repo.nii.ac.jp:00003949","sets":["496:556:559:560:577"]},"author_link":["55371","55372","55377","55373","55375","55374","55370","55376"],"item_3_alternative_title_19":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Studies on the Reactivity of Some Halogenohydrocarbons with Various Metals. IV. : Retarrding or Promoting Action of Various Alcohols, Phenols, Mercaptans, Amines and Some Others on the Reaction between Iron Powder and Benzyl Chloride"}]},"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1966-03","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1/2","bibliographicPageEnd":"47","bibliographicPageStart":"39","bibliographicVolumeNumber":"17","bibliographic_titles":[{"bibliographic_title":"富山大学工学部紀要"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"It was shown in the previous papers that the electro-solution voltage of each metal might be closely correlated to the induction or the rate of the reaction between various metals and benzyl chloride. Futher-more inhibiting or promoting action of some reagents for the reaction between aluminum partic1es and benzyl chloride was reported as an attempt to checking the solvent effect of these reagents on the reaction catalyzed by aluminum chloride. Now using similar additives the reaction between iron powder and benzyl chloride is studied from the same stand-point as is stated above. The result obtained is as follows: \n(1) Mercaptans, amines and amides showed strong inhibiting action, and alcohols showed moderate inhibiting action, whereas most of phenols, nitrobenzene and aluminum triphenolate showed remarkable promoting action. \n(2) It is shown that the form of curve representing the inhibiting or promoting effect is deservedly changed with the variety of the additives and also inf1uenced with temperature in cosiderable extent. \n(3) The promoting effect of nitrobenzene reinforced our suggestion for the presence of suitable range of electric conductivity over which the intermediate complex in the system of catalytic reaction with metallic halide is activated by the ionization or polarization of that in desirable degree. \n(4) One presumption is offered for the explanation of the promoting action of phenols ascribing to the formation of metallic phenolates as the intermediate of the reaction.","subitem_description_type":"Abstract"},{"subitem_description":"著者らはハロゲン化ベンジルと各種の金属との反応についてその進行が金属の電溶圧と密接な関連があることを第1報および第3報において報告したが，後者においてはアルミニウム粒と塩化ベンジルとの反応に対する種々の添加物の影響についてそれらの阻害あるいは促進の様相を塩化アルミニウム触媒反応に対する広い意味の溶媒効果の検討を含めて行なったものである。\n本報では鉄粉と塩化ベンジルとの反応について略類似の添加物類を使用して同じ立場からの研究を進めたものである。","subitem_description_type":"Abstract"}]},"item_3_description_40":{"attribute_name":"資源タイプ(DSpace)","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_3_description_6":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"富山大学工学部紀要，17(1/2)","subitem_description_type":"Other"}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"55374","nameIdentifierScheme":"WEKO"}],"names":[{"name":"ASAOKA, Tadatomo"}]},{"nameIdentifiers":[{"nameIdentifier":"55375","nameIdentifierScheme":"WEKO"}],"names":[{"name":"TSUKURIMITI, Eiiti"}]},{"nameIdentifiers":[{"nameIdentifier":"55376","nameIdentifierScheme":"WEKO"}],"names":[{"name":"TOMITA, Nobuo"}]},{"nameIdentifiers":[{"nameIdentifier":"55377","nameIdentifierScheme":"WEKO"}],"names":[{"name":"HIRATA, Tosio"}]}]},"item_3_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.15099/00003943","subitem_identifier_reg_type":"JaLC"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"富山大学工学部"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00175872","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03871339","subitem_source_identifier_type":"ISSN"}]},"item_3_subject_22":{"attribute_name":"国立国会図書館分類","attribute_value_mlt":[{"subitem_subject":"ZM2","subitem_subject_scheme":"NDLC"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"浅岡, 忠知"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"作道, 栄一"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"冨田, 宣夫"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"平田, 俊雄"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-16"}],"displaytype":"detail","filename":"Kokiyo_17_01_Page039to047.pdf","filesize":[{"value":"6.0 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Kokiyo_17_01_Page039to047.pdf","url":"https://toyama.repo.nii.ac.jp/record/3949/files/Kokiyo_17_01_Page039to047.pdf"},"version_id":"40e95f74-df0c-4beb-9cda-d93007fe4f40"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"ハロゲン化炭化水素","subitem_subject_scheme":"Other"},{"subitem_subject":"金属類との反応性","subitem_subject_scheme":"Other"},{"subitem_subject":"鉄粉と塩化ベンジルとの反応","subitem_subject_scheme":"Other"},{"subitem_subject":"アルコール類","subitem_subject_scheme":"Other"},{"subitem_subject":"フェノール類,","subitem_subject_scheme":"Other"},{"subitem_subject":"メルカプタン類","subitem_subject_scheme":"Other"},{"subitem_subject":"アミン類","subitem_subject_scheme":"Other"},{"subitem_subject":"阻害あるいは促進作用","subitem_subject_scheme":"Other"},{"subitem_subject":"ハロゲン化ベンジル","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"ハロゲン化炭化水素と金属類との反応性の研究(第4報) : 鉄粉と塩化ベンジルとの反応のアルコール類,フェノール類,メルカプタン類,アミン類などの添加による阻害あるいは促進作用","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ハロゲン化炭化水素と金属類との反応性の研究(第4報) : 鉄粉と塩化ベンジルとの反応のアルコール類,フェノール類,メルカプタン類,アミン類などの添加による阻害あるいは促進作用"}]},"item_type_id":"3","owner":"3","path":["577"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-09-24"},"publish_date":"2012-09-24","publish_status":"0","recid":"3949","relation_version_is_last":true,"title":["ハロゲン化炭化水素と金属類との反応性の研究(第4報) : 鉄粉と塩化ベンジルとの反応のアルコール類,フェノール類,メルカプタン類,アミン類などの添加による阻害あるいは促進作用"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-07-25T15:13:49.071129+00:00"}