{"created":"2023-07-25T09:05:48.794566+00:00","id":3948,"links":{},"metadata":{"_buckets":{"deposit":"62d62396-f714-4548-aad7-5a33e12dad2e"},"_deposit":{"created_by":3,"id":"3948","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3948"},"status":"published"},"_oai":{"id":"oai:toyama.repo.nii.ac.jp:00003948","sets":["496:556:559:560:577"]},"author_link":["55369","55366","55365","55363","55364","55362","55367","55368"],"item_3_alternative_title_19":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Retarding Action of Various Metallic Salts of some Aromatic Carboxylic Acid on the Reaction between Aluminum Particles and Carbon Tetrachloride"}]},"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1966-03","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1/2","bibliographicPageEnd":"38","bibliographicPageStart":"32","bibliographicVolumeNumber":"17","bibliographic_titles":[{"bibliographic_title":"富山大学工学部紀要"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"In the preceding paper it was shown that the reaction between aluminum particles and carbon tetrachloride was ionic considering the relation of the induction period with each metallic salt versus their electric conductivity. Now the simi1ar studies using various metallic salts of some aromatic carboxylic acid which may ionize in the organic solvent are carried out. The result obtained is as follows: \n(1) In the influence of water of crystallization on the induction period the linear relation was not found between the critical concentration of the induction period and the water content, as was suggested by M. Stern， and it is explained that its discrepancy came from the difference of each temperature at which water was liberated. \n(2) For the 6 sorts of aromatic carboxylic acids the order of the prolonged effect is as follows: salicylic -> methylenedisalicylic -> alkylsalicylates > benzoic-. \n(3) In various metallic salts of aromatic carboxylic acid, metallic salicylates or metallic methylenedisalicylates gave the negative effects compared with respective acid, while metallic benzoates gave the positive effects. \n(4) Since various metallic salts of aromatic carboxylic acid have respectively specified ionizing abi1ity in the organic solvent, some relation of the critical concentration to the induction period versus the specific coductivity is obtained.","subitem_description_type":"Abstract"},{"subitem_description":"著者達の研究室では従来Al粒とCCl_4との反応について，各種阻害剤の添加効果の研究を行なって来ている。\nこれと関連して前報においては有機溶媒中で電離性のあるジイソプロピルサリチル酸塩（本稿中ではDips塩と略記する）の添加効果について報告し，この反応系の阻害作用は導電率と密接な関係があることを認め，これらの反応がある程度イオン的に進むことを指摘した。\n本報ではこれに引続いて芳香族カルボン酸として安息香酸，サリチル酸およびメチレンジサリチル酸（本稿中ではM.D.S.Aと略記する）の各種金属塩の添加による阻害作用について報告する。","subitem_description_type":"Abstract"}]},"item_3_description_40":{"attribute_name":"資源タイプ(DSpace)","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_3_description_6":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"富山大学工学部紀要，17(1/2)","subitem_description_type":"Other"}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"55366","nameIdentifierScheme":"WEKO"}],"names":[{"name":"ASAOKA, Tadatomo"}]},{"nameIdentifiers":[{"nameIdentifier":"55367","nameIdentifierScheme":"WEKO"}],"names":[{"name":"SHIMASAKI, Choichiro"}]},{"nameIdentifiers":[{"nameIdentifier":"55368","nameIdentifierScheme":"WEKO"}],"names":[{"name":"TOYOTA, Kenitiro"}]},{"nameIdentifiers":[{"nameIdentifier":"55369","nameIdentifierScheme":"WEKO"}],"names":[{"name":"TANIGUTI, Mikio"}]}]},"item_3_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.15099/00003942","subitem_identifier_reg_type":"JaLC"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"富山大学工学部"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00175872","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03871339","subitem_source_identifier_type":"ISSN"}]},"item_3_subject_22":{"attribute_name":"国立国会図書館分類","attribute_value_mlt":[{"subitem_subject":"ZM2","subitem_subject_scheme":"NDLC"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"浅岡, 忠知"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"島崎, 長一郎"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"豊田, 絢一郎"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"谷口, 美紀生"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-16"}],"displaytype":"detail","filename":"Kokiyo_17_01_Page032to038.pdf","filesize":[{"value":"5.9 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Kokiyo_17_01_Page032to038.pdf","url":"https://toyama.repo.nii.ac.jp/record/3948/files/Kokiyo_17_01_Page032to038.pdf"},"version_id":"3f6b8047-66c2-4728-a678-266c8b3c5247"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"アルミニウム粒","subitem_subject_scheme":"Other"},{"subitem_subject":"四塩化炭素","subitem_subject_scheme":"Other"},{"subitem_subject":"芳香族カルボン酸塩添加","subitem_subject_scheme":"Other"},{"subitem_subject":"阻害作用","subitem_subject_scheme":"Other"},{"subitem_subject":"比導電率","subitem_subject_scheme":"Other"},{"subitem_subject":"臨界モル濃度","subitem_subject_scheme":"Other"},{"subitem_subject":"イオン化能","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"アルミニウム粒と四塩化炭素との反応の芳香族カルボン酸塩添加による阻害作用","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"アルミニウム粒と四塩化炭素との反応の芳香族カルボン酸塩添加による阻害作用"}]},"item_type_id":"3","owner":"3","path":["577"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-09-24"},"publish_date":"2012-09-24","publish_status":"0","recid":"3948","relation_version_is_last":true,"title":["アルミニウム粒と四塩化炭素との反応の芳香族カルボン酸塩添加による阻害作用"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-07-25T15:13:48.061195+00:00"}