@article{oai:toyama.repo.nii.ac.jp:00003922,
 author = {浅岡, 忠知 and 作道, 栄一 and 常本, 大英 and 長瀬, 汎},
 issue = {1/2},
 journal = {富山大学工学部紀要},
 month = {Mar},
 note = {ln the previous papers it has been believed that the reaction between various metals and benzyl halides or alkyl chlorides is ionic considering the relation between the induction period with each metal and their electro-solution voltage. Now inhibiting or promoting power of some reagent for the reaction between aluminum particles and benzyl chloride is studied and checked also their solvent effects. The result obtained is as follows: 
(1) 4 sorts of mercaptans retarded this reaction whereas many alcohols and phenols promoted them, and further this promoting action is increased in accordance with lowering the reaction temperature and extremely enhanced by optimum quantity of these reagents at 70℃. 
(2) For the 5 sorts of amines the order of inhibiting power was benzyl-> β-naphthyl-> α-naphtyl-> aniline> lauryl-. This resembled with the orders of inhibiting power of alcohols and mercaptans for the reaction between aluminum particles and carbontetrachlorde as benzyl-> phenyl-> lauryl-. 
(3) The addition of ligroin showed the promoting effect over the considerable wide range in which the range of 1.O--10.5g was striking and the addition of nitrobenzene also showed the promting effect over the range of 0.05--0.5g. This solvent effect was remarkable rather than resemble to that of the reaction between aluminum particles and carbontetrachloride, and this results would support our presumption for the presence of suitable range of electrolytic conductivity over which the system of catalytic reaction with metallic halide acts ionically., 第1報はハロゲン化ベンジルと各種の金属との反応について，第2報は3種の塩化アルキルと各種の金属あるいは塩化金属との反応についての報告であって，これらにおいて反応の進行は金属の電溶圧と密接な関連があることを認めて，これらの反応がイオン的であることを指摘しさらに塩化ベンジルと銅，鉄，アルミニウムとの反応については無極性の溶媒であるリグロインの添加によって反応が緩和されあるいは促進されることを認めている。
本報ではアルミニウム粒と塩化ベンジルとの反応について添加物の影響を広い意味の溶媒効果の検討を含めて行ったものである。, Article, 富山大学工学部紀要，16(1/2)},
 pages = {84--91},
 title = {ハロゲン化炭化水素と金属類との反応性の研究(第3報) : アルミニウム粒と塩化ベンジルとの反応のメルカプタン類,アルコール類,フェノール類,アミン類などの添加による阻害あるいは促進作用},
 volume = {16},
 year = {1965}
}