@article{oai:toyama.repo.nii.ac.jp:00003921, author = {浅岡, 忠知 and 作道, 栄一 and 松井, 竜三 and 鷲北, 憲次}, issue = {1/2}, journal = {富山大学工学部紀要}, month = {Mar}, note = {In the preceding paper it was shown that considerably available results had been obtained by the addition of many sorts of metals or inorganic salts to the AlCl_3 or FeCl_3 as the catalyst for the reactions, such as the ketone synthesis, the polymerization of olefins etc. Now the similar studies on the reactions which take up on the head are carried out. The results obtained are given in following summaries. (1) Effects of 11 sorts of metals and 7 sorts of inorganic salts are studied for the isomerization of α-bromonaphthalene or butylnaphthalene to β-compounds and the polymerization of cyclohexene or dodecene with TaCl_5 (2) Many sorts of metals and inorganic salts gave the positive effects. (3) In the case of the isomerization of butylnaphthalene to β-derivertive, the order of effect became just reverse to that for the disproportionation of butylnaphthalene with AlCl_3. (4) The difference between the order of effects obtained for the isomerizetion of α-bromonaphthalne to β-compound with TaCl_5 and that for the same reaction with AlCl_3 and FeCl_3 in the lene to β-compound with TaCl_5 and that for the same reaction with AlCl_3 and FeCl_3 in the previous reports were checked. (5) The optimum quantiy in respective substance required to enhance the polymerization of olefins with TaCl_5 was nearly equal to that for the other reactions in the preceding reports., 無水塩化アルミニウム系触媒に金属類または無機塩類などの他物質を添加して種々の反応を行なった際の効果に関する研究については,すでに報告してきている。 本報は無水五塩化タンタルを触媒とした際の添加物の効果を掲題の反応について検討したものである。, Article, 富山大学工学部紀要,16(1/2)}, pages = {78--83}, title = {無水塩化アルミニウム系触媒に対する他物質添加の影響の研究(第7報)}, volume = {16}, year = {1965} }