@article{oai:toyama.repo.nii.ac.jp:00003856, author = {浅岡, 忠知 and 作道, 栄一 and 島田, 正成 and 渡辺, 孜}, issue = {1/2}, journal = {富山大学工学部紀要}, month = {Mar}, note = {In the preceding paper it was shown that considerably available results were obtained by the addition of many sorts of metals or inorganic salts to the AlCl_3 or FeCl_3 as the catalyst for the reaction of Ketone synthesis, the polimerization of olefins, the alkylation of benzene with alkyl chlorides and the isomerization of α-bromonaphthalene to β-compound respectively. Now the similar studies on the disrroportionation of dodecyl benzene or octadecyl benzene with AlCl_3 are carried out. The results obtained are given in the fllowing summary. (1) Effects of 11 sorts of metals and 5 sorts of inorganic salts are studied for the disproportionation of dodecyl benzenc or octadecyl benzene with AlCl_3. (2) Many sorts of metals and inorganic salts geve the positive effects. (3) As the searching of the optimum in respective substance required to obtain the enhanced effect, the mol ratio of these substances to AlCl_3 catalyst were checked. (4) These results roughly resembled with the outline for the effect of various metals and inorganic salts in the preceding reports e.g. the alkylation reaction of benzene with allkyl chlorides., 無水塩化アルミニウム又は無水塩化鉄触媒に金属類や無機塩類などを添加した場合の効果について,既に一連の研究としてケトン合成反応,オレフィン重合反応,ベンゼンのアルキル化反応,α-プロモナフタレンの異性化反応について行っており,いずれも目的反応に対して正効果のある諸添加物の相当数ある事が判った。 本報においては更にアルキルベンゼンの移換反応の際の添加効果について検討した。, Article, 富山大学工学部紀要,14(1/2)}, pages = {167--73}, title = {無水塩化アルミニウム系触媒に対する他物質添加の影響の研究(第5報) : ドデシルおよびオクタデシルベンゼンの移換反応の際の触媒としての無水塩化アルミニウムに対する各種金属無機塩類などの添加効果について}, volume = {14}, year = {1963} }