@article{oai:toyama.repo.nii.ac.jp:00003822, author = {浅岡, 忠知 and 安川, 三郎 and 松井, 不二雄 and 横道, 孝二 and 作道, 栄一}, issue = {1/2}, journal = {富山大学工学部紀要}, month = {Mar}, note = {In the preceding papers it was shown that considerably available results were obtained by the addition of many sorts of metals or inorganic salts to the AICl_3 or FeCl_3 as the calalyst for the reaction of ketone-synthesis, the polymerization of olefins and the alkylation of benzene with alkyl chlorides respepectively. Now the similar studies on the isomerization of α-bromonaphtalene to β-compound with AlCl_3 or FeCl_3 are carried out. The results obtained are given in the following summary. (I) Predetermining the regular relation between each β-compound content in monobrom-onaphthalene mixtures and their density or melting point, respective degree of isomerization might be presumed depending on such physical constant of purified reaction products. (II) Many sorts of metals and few inorganic salts gave the positive effects using the definite quantities of them namely half mol or half weight of each catalyst, but no enhanced effect with variation of their quantities was checked. (III) These results roughly resembled with the outline for the effect of various metals and inorganic salts in the preceding reports., 著者等は従来無水塩化アノレミニウムまたは無水塩化鉄触媒に各種の金属或は無機塩類などを添加した際の効果についての研究を行って来ており,既に前報までにケトン合成反応についてはケトンの収率を10%以上増加する能力ある添加物が相当数あり,オレフィン重合反応に就いては重合生物の平均分子量を増加する効果のある添加物が可成りあり,更にベンゼンのアルキル化の反応についてはアルキル基の導入を増す効果即ち正効果を生ずる添加物が相当ある事を認めて来ている。 本報に於てはナフタレン核に於ての臭素のα-位よりβ-位への移動の反応について類縁の研究を行ったものである。, Article, 富山大学工学部紀要,13(1/2)}, pages = {85--93}, title = {無水塩化アルミニウム系触媒に対する他物質添加の影響の研究(第4報) : α-ブロモナフタレンのβ-誘導体への異性化の際の触媒としての無水塩化アルミニウムまたは無水塩化鉄に対する各種金属無機塩類などの添加効果について}, volume = {13}, year = {1962} }