{"created":"2023-07-25T09:05:42.094504+00:00","id":3819,"links":{},"metadata":{"_buckets":{"deposit":"3c6e245d-cceb-4bc0-b8d5-853f38f5b8df"},"_deposit":{"created_by":3,"id":"3819","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3819"},"status":"published"},"_oai":{"id":"oai:toyama.repo.nii.ac.jp:00003819","sets":["496:556:559:560:573"]},"author_link":["54926","54927"],"item_3_alternative_title_19":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Measurements of the Velocity Constant of Chlorate Formation"}]},"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1962-03-20","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1/2","bibliographicPageEnd":"74","bibliographicPageStart":"73","bibliographicVolumeNumber":"13","bibliographic_titles":[{"bibliographic_title":"富山大学工学部紀要"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The velocity constant of the reaction: \n2HClO + ClO^- → 2H^+ + 2Cl^- + ClO_3a^- that is, K in the formula:  -dC_ClO-/dt = KC_HClO^2C_ClO^- was measured at 25℃, the total sum of the concentrations of the constituents being 3.42 or 4.81 (mole/l). K increased with time.","subitem_description_type":"Abstract"},{"subitem_description":"いわゆる徴酸性法におけるクロレート生成反応の機構はFoester以来の通説により \n2^<HClO> + ClO^- → 2^<H^+> + 2^<Cl^-> + ClO_3^- (1) \n2^<H^+> + 2^<ClO^-> → 2^<HClO> (2) \n3^<ClO^-> → 2^<Cl^-> + ClO_3 (3) \nで，(1)が律速段階とされる。\nこの(1)の速度定数，即ち-dC_<ClO^->/dt = KC_<HCLO^2>C_<ClO^->のKについてはFoerster, Sand, Knibbsら，今川の測定がある。\nKは温度により変るのは勿論であり，なお液のイオン強度の影響を強く受けるので，上記測定値はいずれも別報の場合は用い得ない。\nよってこの測定を行った。\n測定範囲は狭いが一つの“ノート”としてあえて報告する。","subitem_description_type":"Abstract"}]},"item_3_description_40":{"attribute_name":"資源タイプ(DSpace)","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_3_description_6":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"富山大学工学部紀要，13(1/2)","subitem_description_type":"Other"}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"54927","nameIdentifierScheme":"WEKO"}],"names":[{"name":"YOKOYAMA, Tatsuo"}]}]},"item_3_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.15099/00003813","subitem_identifier_reg_type":"JaLC"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"富山大学工学部"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00175872","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03871339","subitem_source_identifier_type":"ISSN"}]},"item_3_subject_22":{"attribute_name":"国立国会図書館分類","attribute_value_mlt":[{"subitem_subject":"ZM2","subitem_subject_scheme":"NDLC"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"横山, 辰雄"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-16"}],"displaytype":"detail","filename":"Kokiyo_13_01_Page073to074.pdf","filesize":[{"value":"6.8 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Kokiyo_13_01_Page073to074.pdf","url":"https://toyama.repo.nii.ac.jp/record/3819/files/Kokiyo_13_01_Page073to074.pdf"},"version_id":"2df6d90b-ca67-42ad-bec7-2e20b6e40085"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"クロレート生成反応速度定数","subitem_subject_scheme":"Other"},{"subitem_subject":"徴酸性法","subitem_subject_scheme":"Other"},{"subitem_subject":"律速段階","subitem_subject_scheme":"Other"},{"subitem_subject":"Foerster","subitem_subject_scheme":"Other"},{"subitem_subject":"Sand","subitem_subject_scheme":"Other"},{"subitem_subject":"Knibbs","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"クロレート生成反応速度定数の若干の測定","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"クロレート生成反応速度定数の若干の測定"}]},"item_type_id":"3","owner":"3","path":["573"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-09-19"},"publish_date":"2012-09-19","publish_status":"0","recid":"3819","relation_version_is_last":true,"title":["クロレート生成反応速度定数の若干の測定"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-07-25T15:15:39.381864+00:00"}