{"created":"2023-07-25T09:05:38.910275+00:00","id":3744,"links":{},"metadata":{"_buckets":{"deposit":"645da242-895b-4414-a1e4-70e9adbf1cb2"},"_deposit":{"created_by":3,"id":"3744","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3744"},"status":"published"},"_oai":{"id":"oai:toyama.repo.nii.ac.jp:00003744","sets":["496:556:559:560:571"]},"author_link":["54481","54484","54483","54482","54476","54479","54478","54477","54480","54475"],"item_3_alternative_title_19":{"attribute_name":"その他(別言語等)のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Effects of Various Substance on the Anhydrous Aluminum Chloride or Allied Catalyst II : Effects of Various Metals and Inorganic Salts on the Aluminum Chloride or Ferric Chloride for the Polymerization of Olefins"}]},"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1960-03-20","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1/2","bibliographicPageEnd":"69","bibliographicPageStart":"60","bibliographicVolumeNumber":"11","bibliographic_titles":[{"bibliographic_title":"富山大学工学部紀要"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"In the previous paper, about 10% increase of yields were shown by the addition of many sorts of metals, alloys and inorganic salts to the FeCl_3 a catalyst for the two kinds of the reaction of ketone-synthesis. Now the similar studies on the polymerization of olefins are carried out using AlCl_3 or FeCl_3 catalyst accompanied with various metals or inorganic salts, because these reactions are known to have the mechanism followed by the way of addition with HCl, but not produce HCl as the byproduct differing from the reaction of ketone-synthesis. The results obtained are given in the following summary. \n(I) Effects of the 13 sorts of metals and 6 sorts of inorganic salts are studied for the polymerization of 3 sorts of olefins i.e. cetene, dodecene and cyclohexene with AlCl_3 or FeCl_3. \n(II) Many sorts of metals and inorganic salts gave the positive effects, but others of these substance gave the negative effects. \n(III) These results roughly resembled with the outline for the effect of various metals and inorganic salts in the previous report.","subitem_description_type":"Abstract"},{"subitem_description":"前報に於てはケトン合成反応の際の触媒としての無水塩化鉄に各種金属,合金類並びに塩類等を添加した際の添加効果について研究し,金属にも,合金にも,無機塩類にもそのケトン収率を10%以上増加するものが相当数ある事を明かにした。\nまたこれに先だって『無水塩化アルミニウム触媒に対する他物質添加の影響(第1報)』として「ケトン台成反応の際の鉄或はアルミニウムの添加効果について」なる本研究の予報に相当する研究を行い,粉状の無水塩化アルミニウムに対して鉄或はアルミニウムを添加する際に1O~15%の収率の向上する事を認めている。\n本報に於ては塩化水素が反応機構に関与するが,それの副生をしないと云う点に於てケトン合成の場合と様相を異にするオレフィン類の重合反応を選び,類似の研究を行ったものである。","subitem_description_type":"Abstract"}]},"item_3_description_40":{"attribute_name":"資源タイプ(DSpace)","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_3_description_6":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"富山大学工学部紀要,11(1/2)","subitem_description_type":"Other"}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"54480","nameIdentifierScheme":"WEKO"}],"names":[{"name":"ASAOKA, Tadatomo"}]},{"nameIdentifiers":[{"nameIdentifier":"54481","nameIdentifierScheme":"WEKO"}],"names":[{"name":"YASUKAWA, Saburo"}]},{"nameIdentifiers":[{"nameIdentifier":"54482","nameIdentifierScheme":"WEKO"}],"names":[{"name":"UEDA, Kazuo"}]},{"nameIdentifiers":[{"nameIdentifier":"54483","nameIdentifierScheme":"WEKO"}],"names":[{"name":"NISI, Hidemi"}]},{"nameIdentifiers":[{"nameIdentifier":"54484","nameIdentifierScheme":"WEKO"}],"names":[{"name":"NOZAKI, Sinkiti"}]}]},"item_3_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.15099/00003738","subitem_identifier_reg_type":"JaLC"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"富山大学工学部"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00175872","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03871339","subitem_source_identifier_type":"ISSN"}]},"item_3_subject_22":{"attribute_name":"国立国会図書館分類","attribute_value_mlt":[{"subitem_subject":"ZM2","subitem_subject_scheme":"NDLC"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"浅岡, 忠知"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"安川, 三郎"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"上田, 和生"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"西, 秀実"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"野崎, 真吉"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-16"}],"displaytype":"detail","filename":"Kokiyo_11_01_Page060to069.pdf","filesize":[{"value":"13.4 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Kokiyo_11_01_Page060to069.pdf","url":"https://toyama.repo.nii.ac.jp/record/3744/files/Kokiyo_11_01_Page060to069.pdf"},"version_id":"505b2fb4-e48d-4131-9f60-ddb715804b84"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"無水塩化アルミニウム系触媒","subitem_subject_scheme":"Other"},{"subitem_subject":"他物質添加の影響","subitem_subject_scheme":"Other"},{"subitem_subject":"オレフィン類","subitem_subject_scheme":"Other"},{"subitem_subject":"重合触媒","subitem_subject_scheme":"Other"},{"subitem_subject":"無水塩化鉄","subitem_subject_scheme":"Other"},{"subitem_subject":"各種金属無機塩類","subitem_subject_scheme":"Other"},{"subitem_subject":"添加効果","subitem_subject_scheme":"Other"},{"subitem_subject":"塩化水素","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"無水塩化アルミニウム系触媒に対する他物質添加の影響の研究(第2報) : オレフィン類の重合触媒としての無水塩化鉄に対する各種金属無機塩類等の添加効果について","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"無水塩化アルミニウム系触媒に対する他物質添加の影響の研究(第2報) : オレフィン類の重合触媒としての無水塩化鉄に対する各種金属無機塩類等の添加効果について"}]},"item_type_id":"3","owner":"3","path":["571"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-09-13"},"publish_date":"2012-09-13","publish_status":"0","recid":"3744","relation_version_is_last":true,"title":["無水塩化アルミニウム系触媒に対する他物質添加の影響の研究(第2報) : オレフィン類の重合触媒としての無水塩化鉄に対する各種金属無機塩類等の添加効果について"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-07-25T15:16:45.464894+00:00"}