{"created":"2023-07-25T09:05:38.648808+00:00","id":3738,"links":{},"metadata":{"_buckets":{"deposit":"3d48ac65-074a-4af6-a0b6-c3dbb5feba56"},"_deposit":{"created_by":3,"id":"3738","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3738"},"status":"published"},"_oai":{"id":"oai:toyama.repo.nii.ac.jp:00003738","sets":["496:556:559:560:571"]},"author_link":["54460","54456","54459","54457","54458","54455"],"item_3_alternative_title_19":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"A study of Acetylene glycols (Part. I) : Synthesis of 2.5-dimethyl-3-hexine-2.5-diol"}]},"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1960-03-20","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1/2","bibliographicPageEnd":"34","bibliographicPageStart":"32","bibliographicVolumeNumber":"11","bibliographic_titles":[{"bibliographic_title":"富山大学工学部紀要"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"When 2.5-dimethyl-3-hexine-2.5-diol is oxidized dehydrated and, esterified, meta-acryliccid ester is effected. This is a well-known starting material of acrylic resins. P. W. Porter has published this subject on the chemical Enginerring 54, NO4. 102--106 (1947) as the new preparation of meta-acrylic acid resins. Some of investigators have reported on the method of preparation, reacting acetylene and acetone in the presence of caustic alkali as condensing agent in some of solvents. We have experimented the synthesis of this diol, using acetone, causti kali and calcium carbide powder in stead of acetylene, and have obtained it on the yield of 46% in the ether, 38.5% in the dioxane respectively.","subitem_description_type":"Abstract"},{"subitem_description":"2.5-ジメチル-3-ヘキシン-2.5-ジオールは酸化，脱水，エステル化によりメタアクリル酸エステルを与える。\nこれについてはR.W.Portervがアクリル酸樹脂の新製法としてアセチレン及びアセトンとリジオールを径てエステル及びポリマーの工業的合成法を報告している。\nアセチレンとアセトンとのカ性カリ存在下の反応についてはZeltnerはジメチルホルマールを溶剤とし，又Weiz-mannはアセタールやエチレングライコールのアルキルエーテルを溶剤としたB・P特許制是唱し，他の英特許ではエチレングライコールブチルエーテルを溶剤とし0℃にて反応を行えば本ジオールを28～10%とメチルブチノール85～66.7%を得ている。\n我々はアセチレンの代りにカルシウムカーバイドとアセトンとを用いジオキサン及びエチルエーテルを溶剤として常庄常温にて所期の物質を合成し若干の知見を得た。","subitem_description_type":"Abstract"}]},"item_3_description_40":{"attribute_name":"資源タイプ(DSpace)","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_3_description_6":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"富山大学工学部紀要，11(1/2)","subitem_description_type":"Other"}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"54458","nameIdentifierScheme":"WEKO"}],"names":[{"name":"NOZI, Sueyosi"}]},{"nameIdentifiers":[{"nameIdentifier":"54459","nameIdentifierScheme":"WEKO"}],"names":[{"name":"IWATA, Hideo"}]},{"nameIdentifiers":[{"nameIdentifier":"54460","nameIdentifierScheme":"WEKO"}],"names":[{"name":"MURANAKA, Isao"}]}]},"item_3_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.15099/00003732","subitem_identifier_reg_type":"JaLC"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"富山大学工学部"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00175872","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03871339","subitem_source_identifier_type":"ISSN"}]},"item_3_subject_22":{"attribute_name":"国立国会図書館分類","attribute_value_mlt":[{"subitem_subject":"ZM2","subitem_subject_scheme":"NDLC"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"野路, 末吉"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"岩田, 英夫"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"村中, 功夫"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-16"}],"displaytype":"detail","filename":"Kokiyo_11_01_Page032to034.pdf","filesize":[{"value":"2.1 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Kokiyo_11_01_Page032to034.pdf","url":"https://toyama.repo.nii.ac.jp/record/3738/files/Kokiyo_11_01_Page032to034.pdf"},"version_id":"c4a45d7d-8739-4a74-a6ad-909df5840526"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"アセチレングライコール類","subitem_subject_scheme":"Other"},{"subitem_subject":"2.5-ジメチル-3-ヘキシン-2.5-ジオール","subitem_subject_scheme":"Other"},{"subitem_subject":"メタアクリル酸エステル","subitem_subject_scheme":"Other"},{"subitem_subject":"R. W. Porterv","subitem_subject_scheme":"Other"},{"subitem_subject":"カルシウムカーバイド","subitem_subject_scheme":"Other"},{"subitem_subject":"アセトン","subitem_subject_scheme":"Other"},{"subitem_subject":"ジオキサン","subitem_subject_scheme":"Other"},{"subitem_subject":"エチルエーテル","subitem_subject_scheme":"Other"},{"subitem_subject":"常庄常温","subitem_subject_scheme":"Other"},{"subitem_subject":"カーバイト粉末","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"アセチレングライコール類の研究(第I報) : 2.5-ジメチル-3-ヘキシン-2.5-ジオールの合成","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"アセチレングライコール類の研究(第I報) : 2.5-ジメチル-3-ヘキシン-2.5-ジオールの合成"}]},"item_type_id":"3","owner":"3","path":["571"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-09-13"},"publish_date":"2012-09-13","publish_status":"0","recid":"3738","relation_version_is_last":true,"title":["アセチレングライコール類の研究(第I報) : 2.5-ジメチル-3-ヘキシン-2.5-ジオールの合成"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-07-25T15:16:39.250301+00:00"}