{"created":"2023-07-25T09:05:37.497643+00:00","id":3711,"links":{},"metadata":{"_buckets":{"deposit":"58b6f6b1-a9da-4861-b537-2e64dbdd2086"},"_deposit":{"created_by":3,"id":"3711","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3711"},"status":"published"},"_oai":{"id":"oai:toyama.repo.nii.ac.jp:00003711","sets":["496:556:559:560:570"]},"author_link":["54386","54384","54389","54385","54388","54387"],"item_3_alternative_title_19":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"On the Cause of the Induction Period of the Reaction between Aluminum and Carbon Tetrachloride"}]},"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1959-03-20","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1/2","bibliographicPageEnd":"65","bibliographicPageStart":"59","bibliographicVolumeNumber":"10","bibliographic_titles":[{"bibliographic_title":"富山大学工学部紀要"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"In order to infer the cause of the induction period of the reaction between aluminium and boiling carbon tetrachloride, the influence of (1) the reaction temperature, (2) the aerial agitation, (3) the addition of several insoluble substances, (4) the treating of aluminium with sodium chromate solution or the heating of aluminium and (5) the addition of water, had been investigated. The outline of the results obtained are as follows:-- The principal cause of the induction period for the aluminium --carbon tetrachloride appears to reside in the natural protective oxide film on aluminium. But the thickness of that film is not primarily responsible, because difference of oxidizing degree gave little effect, which came from heating aluminium at 200 or 600℃ for several hours. And the crystalline states of oxide on aluminium, or still more perhaps the water holding states of the oxide, mainly relate to the induction period. Oxygen and water dissolved in the carbon tetrachloride do not relate to the induction  period, because bubbling of the air and addition of the water had not an etfect. At the reaction temperature sparingly under boiling point of carbon tetrachloride, extremely prolonged induction period had been observed. Thereby the induction period is dependent upon the time necessary for boiling to remove oxygen and any water from the natural protective oxide film on aluminium.","subitem_description_type":"Abstract"},{"subitem_description":"金属アルミニウム（以下Alと略記する）と沸騰四塩化炭素（以下CCl_4と略記する）との反応には，反応の起る前に誘導期が存在する。\nこの誘導期は無水塩化アルミニウムや無水塩化鉄の存在によって短縮され，二トロ化合物やアルコール類等の阻害剤添加によって延長される。\nこれらの供与体試薬添加による延長効果及びその阻害機構については著者の一人浅岡及びその協同研究者によって多数の研究が行われた。\n然し誘導期間そのものの存在原因についてはStem等の報告の他はあまりない。\nStem等はCCl_4中に飽和した水分は誘導期を9倍に，酸素（又は空気）は2倍に延長し，また真空中で熱処理したAl試料は誘導期を殆んど零に短縮すると言う。\nこれらの事実からAl上の自然保護酸化物中の水分及び酸素の含有量が誘導期存在の主原因になるものとした。\n従って沸騰作用中に水分及び酸素が移動除去されるに要する時間が誘導期であるわけである。\n著者等はこれらのことを更に明らかするため(1)CCl_4の沸点よりわずかに低い温度での反応，(2)空気を吹込んで酸素を補給しながらの反応，(3)不溶性物質を添加して沸騰状態を変えた反応，(4)Alを化学処理又は熱処理して酸化皮肢の状態を変えた場合の反応，(5)水分を添加した反応について若干の実験を行った。\n本報ではこれらの実験結果にもとづきStem等の結論と比較して論ずる。","subitem_description_type":"Abstract"}]},"item_3_description_40":{"attribute_name":"資源タイプ(DSpace)","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_3_description_6":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"富山大学工学部紀要，10(1/2), Page 59-65","subitem_description_type":"Other"}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"54387","nameIdentifierScheme":"WEKO"}],"names":[{"name":"YASUKAWA, Saburo"}]},{"nameIdentifiers":[{"nameIdentifier":"54388","nameIdentifierScheme":"WEKO"}],"names":[{"name":"ASAOKA, Tadatomo"}]},{"nameIdentifiers":[{"nameIdentifier":"54389","nameIdentifierScheme":"WEKO"}],"names":[{"name":"HORIOKA, Takasi"}]}]},"item_3_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.15099/00003705","subitem_identifier_reg_type":"JaLC"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"富山大学工学部"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00175872","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03871339","subitem_source_identifier_type":"ISSN"}]},"item_3_subject_22":{"attribute_name":"国立国会図書館分類","attribute_value_mlt":[{"subitem_subject":"ZM2","subitem_subject_scheme":"NDLC"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"安川, 三郎"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"浅岡, 忠知"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"堀岡, 敬"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-16"}],"displaytype":"detail","filename":"Kokiyo_10_01_Page059to065.pdf","filesize":[{"value":"9.9 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Kokiyo_10_01_Page059to065.pdf","url":"https://toyama.repo.nii.ac.jp/record/3711/files/Kokiyo_10_01_Page059to065.pdf"},"version_id":"3fa2f5c4-d7e9-4c83-ad2d-6b6603a0d0cc"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"金属アルミニウム","subitem_subject_scheme":"Other"},{"subitem_subject":"四塩化炭素","subitem_subject_scheme":"Other"},{"subitem_subject":"誘導期の生因","subitem_subject_scheme":"Other"},{"subitem_subject":"沸騰四塩化炭素","subitem_subject_scheme":"Other"},{"subitem_subject":"Sten","subitem_subject_scheme":"Other"},{"subitem_subject":"空気カキマゼ","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"金属アルミニウムと四塩化炭素との反応に於ける誘導期の生因について","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"金属アルミニウムと四塩化炭素との反応に於ける誘導期の生因について"}]},"item_type_id":"3","owner":"3","path":["570"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-09-12"},"publish_date":"2012-09-12","publish_status":"0","recid":"3711","relation_version_is_last":true,"title":["金属アルミニウムと四塩化炭素との反応に於ける誘導期の生因について"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-07-25T15:17:13.933909+00:00"}