{"created":"2023-07-25T09:05:36.056809+00:00","id":3677,"links":{},"metadata":{"_buckets":{"deposit":"ed1f0f4c-bab7-41da-9bf8-bd438028900c"},"_deposit":{"created_by":3,"id":"3677","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3677"},"status":"published"},"_oai":{"id":"oai:toyama.repo.nii.ac.jp:00003677","sets":["496:556:559:560:569"]},"author_link":["54277","54274","54276","54275"],"item_3_alternative_title_19":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Effect of the Addition of Various Metals for the Reaction between Aluminum Particles and Carbon Tetrachloride : I.. On the Case of Iron, Zinc or Titanium added"}]},"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1958-03-20","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1/2","bibliographicPageEnd":"53","bibliographicPageStart":"50","bibliographicVolumeNumber":"9","bibliographic_titles":[{"bibliographic_title":"富山大学工学部紀要"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"For the reaction between aluminum particles and carbon tetrachloride, several studies have been performed by one of the present writers (Asaoka) and his collaborators. Of these studies there were main purposes treating this reaction at the temperature near the boiling point of reaction mixture as the autocatalytic reaction with aluminum chloride, but the worth of this reaction as the representative of reaction between chlorohydrocarbons and metals has been noticed. Then tetrachloethane, pentachloroethane and trichloroethylene have been used for some studies in our laboratory. On the other hand, other metals have been used for only few experiments. In the present paper, the study showed as heading is carried out as the preliminary stage of the reaction between other metals and carbon tetrachloride. The outline of the experimental results are summarized in the following:-- \n(i) For the reaction between aluminum particles and carbon tetrachloride, iron powder, 20 mesh spongy zinc or 20 mesh spongy titanium varied this induction perlod relating their quantities added, and the relation of the both was showed by the somewhat resembling curves having two minimum and one maximum for each case. \n(ii) This reaction was promoted by the addition of iron powder or spongy titanium, and especially this effect was remarkable with the fitted quantities for each metal. It is suggested by this fact that some attention for the treating of aluminum containing these metals with chlorohydrocarbon at the temperature near the boiling point should be paid. \n(iii) The present study is not sufficient to explain the mechanism for the effect of the addition of these metals, but that may be concerned with the chlorides produc ing from these metals.","subitem_description_type":"Abstract"},{"subitem_description":"金属アルミニウムと四塩化炭素との反応については著者の一人浅岡等が昭和21年以来種々の実験を行いその結果を発表して来ており，雑誌『化学』の昭和31年6月号にはその頃までの報告の総括をなしている。\nそれ以後も引続きこの反応に関しての発表をなして来ている。\nこれ等の研究は主として夜相の沸点附近に於けるこの反応を塩化アルミニウム自己触媒反応とて取扱うのを主目標として来たのであるが，これは叉塩素化炭化水素と金属との反応の一つの代表としての価値をも認めて来たものでもある。\nそして塩素化炭化水素としては四塩化エタン，五塩化エタン及びトリクロロエチレン等を用いた実験も一部行って来ているが，一方に於て金属の側についてもアルミニウムの代りにアルミニウム合金とか他の金属とかの場合の反応を定性的には少し行ったりして来たのである。\n先ず鉄粉と四塩化炭素を液相の沸点附近に長時間加熱すれば六塩化エタンの生成が認められるから，これはアルミニウムの場合と全く類似の次式で示される反応が起ったものと推定される。\n6CCl_4 + 2Fe = 3C_2Cl_6 + 2FeCl_3 \nところがこの反応の反応誘導期は極めて長く，自己触媒反応の過程に入ってからも反応の進行は極めて緩徐である。\n更にこの反応は予め塩化鉄や塩化アルミニウムを添加した場合には反応誘導期の可成の知縮が起り，後者の添加の方が著しく良好な事が知られた。\n本報に於てはアルミニウム以外の金属と四塩化炭素との反応の研究の予備段階として標題の研究をなした結果について述べるものである。","subitem_description_type":"Abstract"}]},"item_3_description_40":{"attribute_name":"資源タイプ(DSpace)","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_3_description_6":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"富山大学工学部紀要，9(1/2), Page 50-53","subitem_description_type":"Other"}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"54276","nameIdentifierScheme":"WEKO"}],"names":[{"name":"ASAOKA, Tadatomo"}]},{"nameIdentifiers":[{"nameIdentifier":"54277","nameIdentifierScheme":"WEKO"}],"names":[{"name":"TAZIMA, Hitosi"}]}]},"item_3_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.15099/00003671","subitem_identifier_reg_type":"JaLC"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"富山大学工学部"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00175872","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03871339","subitem_source_identifier_type":"ISSN"}]},"item_3_subject_22":{"attribute_name":"国立国会図書館分類","attribute_value_mlt":[{"subitem_subject":"ZM2","subitem_subject_scheme":"NDLC"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"浅岡, 忠知"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"田島, 仁"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-16"}],"displaytype":"detail","filename":"Kokiyo_9_001_Page050to053.pdf","filesize":[{"value":"7.6 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Kokiyo_9_001_Page050to053.pdf","url":"https://toyama.repo.nii.ac.jp/record/3677/files/Kokiyo_9_001_Page050to053.pdf"},"version_id":"b2a16d59-85df-440d-90de-d7eaacf1e5fa"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"アルミニウム粒","subitem_subject_scheme":"Other"},{"subitem_subject":"四塩化炭素","subitem_subject_scheme":"Other"},{"subitem_subject":"各種金属類添加","subitem_subject_scheme":"Other"},{"subitem_subject":"鉄","subitem_subject_scheme":"Other"},{"subitem_subject":"亜鉛","subitem_subject_scheme":"Other"},{"subitem_subject":"チタニウム","subitem_subject_scheme":"Other"},{"subitem_subject":"金属アルミニウム","subitem_subject_scheme":"Other"},{"subitem_subject":"化学","subitem_subject_scheme":"Other"},{"subitem_subject":"自己触媒反応","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"アルミニウム粒と四塩化炭素との反応の各種金属類添加の影響について(第1報) : 鉄,亜鉛或はチタニウム添加の場合","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"アルミニウム粒と四塩化炭素との反応の各種金属類添加の影響について(第1報) : 鉄,亜鉛或はチタニウム添加の場合"}]},"item_type_id":"3","owner":"3","path":["569"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-09-11"},"publish_date":"2012-09-11","publish_status":"0","recid":"3677","relation_version_is_last":true,"title":["アルミニウム粒と四塩化炭素との反応の各種金属類添加の影響について(第1報) : 鉄,亜鉛或はチタニウム添加の場合"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-07-25T15:17:39.941363+00:00"}