{"created":"2023-07-25T09:05:34.228711+00:00","id":3642,"links":{},"metadata":{"_buckets":{"deposit":"438404c7-01a8-444b-9400-f4bc612b17ed"},"_deposit":{"created_by":3,"id":"3642","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3642"},"status":"published"},"_oai":{"id":"oai:toyama.repo.nii.ac.jp:00003642","sets":["496:556:559:560:568"]},"author_link":["54183","54184","54186","54185"],"item_3_alternative_title_19":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"The Conductance of Several Ketone Complexes with Aluminum Chloride in Ethyl Bromide at 30℃"}]},"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1957-03-20","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1/2","bibliographicPageEnd":"58","bibliographicPageStart":"51","bibliographicVolumeNumber":"8","bibliographic_titles":[{"bibliographic_title":"富山大学工学部紀要"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"In order to investigate the mechanism of the retardation of the reaction between metallic aluminum and carbon tetrachloride due to the addition of inhibitors, the conductance of aluminum chloride in ethyl bromide on addition of inhibitors, such as acetophenone, benzophenone, cyclohexanone or acetone, has been measured. And the order of the strength of the inhibiting action of these ketones has been presumed from the estimation of the conductance mentioned above. The order of the strength thus presumed agrees with the order presumed from the measurements of the induction periods of the reaction between aluminum particles and carbon tetrachloride adding these ketones. Namely it is found the larger conductance of ketone complex with aluminum chloride makes the weaker strength of the inhibiting action of its ketone.","subitem_description_type":"Abstract"},{"subitem_description":"金属アルミニウムと四塩化炭素を反応せしめると六塩化エタンと塩化アルミニウム（以下AlCl_3と記する）をつくるが，この反応には反応誘導期がある。この誘導期はAlCl_3の添加によてて短縮されケトン等の阻害剤によって延長される。阻害剤としてケトン，オレフィン，ニトロ化合物，アルコール類，エーテル類を添加した場合の誘導期の延長効果については既に発表した。\nその阻害の機構は種々考えられるが最も主なものはこれら阻害剤が反応初期生成のAlCl_3を捕捉するためと推定される。而してその阻害作用の大きい小さいについては捕捉生成物即ちAlCl_3と阻害剤の間の錯化合物の性状が問題となる筈である。従来AlCl_3の触媒機構はイオン的であるとされているのでこの阻害の機構を調べるには四塩化炭素中のAlCl_3と阻害剤との錯化合物の電導度を測定するのが最も妥当であると思われる。ところがAlCl_3は四塩化炭素に対して溶解度が非常に小さいので電導度測定の溶媒としては不適当のようである。そこで(1)AlCl_3をよく溶解し(2)常温で液体であること(3)四塩化炭素と同様にAlCl_3と配位結合し得るハロゲンを有する化合物であること等の条件を具えた溶媒として臭化エチルを選んだ。また阻害剤としてアセトフェノン，ベンゾフェノン，シクロヘキサノン，アセトンの四種のケトンを使った。即ち臭化エチル中のAlCl_3とこれらのケトンとの錯化合物の電導度を30℃に於て測定した。臭化エチル中のこれら錯化合物の性状は必ずしも四塩化炭素中のそれと一致するとは限らないが，測定結果によると電導度の大きいケトン程阻害作用が小さいと言う順序になるので以下にその結果の概略を報告する。","subitem_description_type":"Abstract"}]},"item_3_description_40":{"attribute_name":"資源タイプ(DSpace)","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_3_description_6":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"富山大学工学部紀要，8(1/2), Page 51-58","subitem_description_type":"Other"}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"54185","nameIdentifierScheme":"WEKO"}],"names":[{"name":"YASUKAWA, Saburo"}]},{"nameIdentifiers":[{"nameIdentifier":"54186","nameIdentifierScheme":"WEKO"}],"names":[{"name":"ASAOKA, Tadatomo"}]}]},"item_3_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.15099/00003636","subitem_identifier_reg_type":"JaLC"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"富山大学工学部"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00175872","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"3871339","subitem_source_identifier_type":"ISSN"}]},"item_3_subject_22":{"attribute_name":"国立国会図書館分類","attribute_value_mlt":[{"subitem_subject":"ZM2","subitem_subject_scheme":"NDLC"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"安川, 三郎"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"浅岡, 忠知"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-16"}],"displaytype":"detail","filename":"Kokiyo_8_001_Page051to058.pdf","filesize":[{"value":"14.2 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Kokiyo_8_001_Page051to058.pdf","url":"https://toyama.repo.nii.ac.jp/record/3642/files/Kokiyo_8_001_Page051to058.pdf"},"version_id":"bc756415-b3eb-440e-983d-bad1027e24d2"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"臭化エチル","subitem_subject_scheme":"Other"},{"subitem_subject":"塩化アルミニウム-ケトン錯塩","subitem_subject_scheme":"Other"},{"subitem_subject":"電導度","subitem_subject_scheme":"Other"},{"subitem_subject":"金属アルミニウム","subitem_subject_scheme":"Other"},{"subitem_subject":"四塩化炭素","subitem_subject_scheme":"Other"},{"subitem_subject":"六塩化エタン","subitem_subject_scheme":"Other"},{"subitem_subject":"塩化アルミニウム","subitem_subject_scheme":"Other"},{"subitem_subject":"アセトフェノン","subitem_subject_scheme":"Other"},{"subitem_subject":"ベンゾフェノン","subitem_subject_scheme":"Other"},{"subitem_subject":"シクロヘキサノン","subitem_subject_scheme":"Other"},{"subitem_subject":"反応誘導期","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"臭化エチル中の塩化アルミニウム-ケトン錯塩の電導度について","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"臭化エチル中の塩化アルミニウム-ケトン錯塩の電導度について"}]},"item_type_id":"3","owner":"3","path":["568"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-08-31"},"publish_date":"2012-08-31","publish_status":"0","recid":"3642","relation_version_is_last":true,"title":["臭化エチル中の塩化アルミニウム-ケトン錯塩の電導度について"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-07-25T15:18:11.487718+00:00"}