{"created":"2023-07-25T09:05:32.222755+00:00","id":3609,"links":{},"metadata":{"_buckets":{"deposit":"46fd5bec-80dc-4dbe-a39d-2d3b8c2f446a"},"_deposit":{"created_by":3,"id":"3609","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3609"},"status":"published"},"_oai":{"id":"oai:toyama.repo.nii.ac.jp:00003609","sets":["496:556:559:560:567"]},"author_link":["54113","54115","54112","54114","54111","54110"],"item_3_alternative_title_19":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"On the Electro-deposition of Metallic Selenium (the 5th Report) : On the Nitric and Hydrochloric Acid Baths"}]},"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1956-02-29","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1/2","bibliographicPageEnd":"79","bibliographicPageStart":"76","bibliographicVolumeNumber":"7","bibliographic_titles":[{"bibliographic_title":"富山大学工学部紀要"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The nitric and hydrochloric acid baths were investigated as the electrolytic bath of metallic Se. The results are as follows :-- \n(1) In order to deposit Se from nitric acid bath, it is necessary that the concentration of acid under 5n, and more the deposits from nitric acid bath are not favorable. \n(2) In hydrochloric acid bath, Se deposits in any concentration until 12n, but no favorable deposit is obtained under 10n.","subitem_description_type":"Abstract"},{"subitem_description":"前報迄は主として硫酸々性浴からのセレンの電着について報告してきた。而して金属セレンを電着せしめるには浴の酸性度を相当高める必要があり18n付近が最適であることがHippel等の報告及び著者等の追試実験によって明らかになった。またHippel等は同報告に於て硫酸以外の他の酸性浴に於ても成功したと附記している。0.5n以下の稀薄な硝酸及び塩酸浴からの電着については既に著者等の報告したところであるが非金属状のものの含有最が多く金属性結晶核は点在する程度であった。そこで硫酸の場合と同様に濃厚な硝酸浴又は塩酸浴を用いれば金属状セレンを電着せしめ得るものと期待される。但し最適電解温度は90～100℃と云う高温なので濃硝酸や濃塩酸の場合には析出セレンを溶解するのではないかと云う疑問は起る。また普通には境酸の最高濃度は12nであり硫酸の場合のように高い酸性度迄の実験を行うことは出来ない。然し硝酸浴又は塩酸浴からは蒸発乾固し昇華することにより容易に酸化セレンを回収出来ると云う利点がある。而してHippel等の報告には硫酸以外の他の酸の浴については実験値が示されていない。そこで著者等は12n 迄の濃厚な硝酸浴及び塩酸浴についてセレンの電着を試みてみた。本稿ではその概略を報告する。","subitem_description_type":"Abstract"}]},"item_3_description_40":{"attribute_name":"資源タイプ(DSpace)","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_3_description_6":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"富山大学工学部紀要，7(1/2), Page 76-79","subitem_description_type":"Other"}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"54113","nameIdentifierScheme":"WEKO"}],"names":[{"name":"YASUKAWA, Saburo"}]},{"nameIdentifiers":[{"nameIdentifier":"54114","nameIdentifierScheme":"WEKO"}],"names":[{"name":"IZAKI, Tosio"}]},{"nameIdentifiers":[{"nameIdentifier":"54115","nameIdentifierScheme":"WEKO"}],"names":[{"name":"KAMETANI, Keiiti"}]}]},"item_3_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.15099/00003603","subitem_identifier_reg_type":"JaLC"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"富山大学工学部"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00175872","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03871339","subitem_source_identifier_type":"ISSN"}]},"item_3_subject_22":{"attribute_name":"国立国会図書館分類","attribute_value_mlt":[{"subitem_subject":"ZM2","subitem_subject_scheme":"NDLC"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"安川, 三郎"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"位崎, 敏男"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"龜谷, 啓一"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-16"}],"displaytype":"detail","filename":"Kokiyo_7_01_Page076to079.pdf","filesize":[{"value":"8.5 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Kokiyo_7_01_Page076to079.pdf","url":"https://toyama.repo.nii.ac.jp/record/3609/files/Kokiyo_7_01_Page076to079.pdf"},"version_id":"694f686b-c115-4c55-b811-997ec15be379"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"セレン","subitem_subject_scheme":"Other"},{"subitem_subject":"電着","subitem_subject_scheme":"Other"},{"subitem_subject":"硝酸浴","subitem_subject_scheme":"Other"},{"subitem_subject":"塩酸浴","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"セレンの電着に関する研究(第5報) : 硝酸浴及び塩酸浴について","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"セレンの電着に関する研究(第5報) : 硝酸浴及び塩酸浴について"}]},"item_type_id":"3","owner":"3","path":["567"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-08-21"},"publish_date":"2012-08-21","publish_status":"0","recid":"3609","relation_version_is_last":true,"title":["セレンの電着に関する研究(第5報) : 硝酸浴及び塩酸浴について"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-07-25T15:18:47.460922+00:00"}