{"created":"2023-07-25T09:05:32.179956+00:00","id":3608,"links":{},"metadata":{"_buckets":{"deposit":"55e8423e-2635-47d5-a8e0-183a18ddae1b"},"_deposit":{"created_by":3,"id":"3608","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3608"},"status":"published"},"_oai":{"id":"oai:toyama.repo.nii.ac.jp:00003608","sets":["496:556:559:560:567"]},"author_link":["54088","54086","54087","54089","54084","54085"],"item_3_alternative_title_19":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"On the Electro-deposition of metallic Selenium (the 4th Report) : Effects of Acetic Acid, Ethyl Alcohol and Surface Active Agents"}]},"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1956-02-29","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1/2","bibliographicPageEnd":"76","bibliographicPageStart":"71","bibliographicVolumeNumber":"7","bibliographic_titles":[{"bibliographic_title":"富山大学工学部紀要"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The authors already reported about the pitting hole which occured in electrolysis of conc sulphuric acid bath. In this report, we express about the preventing effects of several additions for the piiting phenomena. \n(1) Addition of glacial acetic acid (about 10%) or ethyl alcohol (about 5%) prevents the occurrence of pitting hole perfectly, but the deposit increases the content of black non-metallic Se and becomes flaky. \n(2) Addition of β-naphthalenesulfonic acid (about 0.5%) or p-phenolsulfonic acid salt (about 0.03%) prevents the occurrence of pitting hole perfectly, and also ash-coloured and smooth deposit is obtained. But their excess pollute the plating bath by precipitation of red colloidal Se.","subitem_description_type":"Abstract"},{"subitem_description":"前報こ於ては18n硫酸浴からのセレンの電着について報告した。即ちSeO_2 850gを18n硫酸1Lに溶解した浴を用い温度95℃，電流密度20A/d㎡でニッケル陰極板に硬質で良好な金属セレンを電着せしめ得るが相当に程度のひどいpitting holeを生ずる。\n金属セレンを電着せしめるには水素イオン濃度を相当高くする必要があることはHippel等の報告及び著者等の報告であきらかであるので，やはり濃硫酸を基浴として用いる必要がある。而して硫酸浴は表面張力が可なり高いので，これがpitting holeを生ずる一原因ともなる。そこで本報に於ては18n硫酸基浴に酷酸，アルコール或は界面活性剤を添加し浴の表面張力を引下げて電着を試みてみた。以下にこれらの電着結果について概略を報告する。","subitem_description_type":"Abstract"}]},"item_3_description_40":{"attribute_name":"資源タイプ(DSpace)","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_3_description_6":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"富山大学工学部紀要，7(1/2), Page 71-76","subitem_description_type":"Other"}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"54087","nameIdentifierScheme":"WEKO"}],"names":[{"name":"YASUKAWA, Saburo"}]},{"nameIdentifiers":[{"nameIdentifier":"54088","nameIdentifierScheme":"WEKO"}],"names":[{"name":"IZAKI, Tosio"}]},{"nameIdentifiers":[{"nameIdentifier":"54089","nameIdentifierScheme":"WEKO"}],"names":[{"name":"KAMETANI, Keiiti"}]}]},"item_3_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.15099/00003602","subitem_identifier_reg_type":"JaLC"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"富山大学工学部"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00175872","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03871339","subitem_source_identifier_type":"ISSN"}]},"item_3_subject_22":{"attribute_name":"国立国会図書館分類","attribute_value_mlt":[{"subitem_subject":"ZM2","subitem_subject_scheme":"NDLC"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"安川, 三郎"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"位﨑, 敏男"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"龜谷, 啓一"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-16"}],"displaytype":"detail","filename":"Kokiyo_7_01_Page071to076.pdf","filesize":[{"value":"12.1 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Kokiyo_7_01_Page071to076.pdf","url":"https://toyama.repo.nii.ac.jp/record/3608/files/Kokiyo_7_01_Page071to076.pdf"},"version_id":"8326a23b-4582-4f9f-b9f7-1d3973eace6c"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"セレン","subitem_subject_scheme":"Other"},{"subitem_subject":"電着","subitem_subject_scheme":"Other"},{"subitem_subject":"濃硫酸浴","subitem_subject_scheme":"Other"},{"subitem_subject":"アルコール","subitem_subject_scheme":"Other"},{"subitem_subject":"醋酸","subitem_subject_scheme":"Other"},{"subitem_subject":"金属セレン","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"セレンの電着に関する研究(第4報) : 濃硫酸浴(その2) : 醋酸,アルコール及び界面活性剤添加の影響について","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"セレンの電着に関する研究(第4報) : 濃硫酸浴(その2) : 醋酸,アルコール及び界面活性剤添加の影響について"}]},"item_type_id":"3","owner":"3","path":["567"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-08-21"},"publish_date":"2012-08-21","publish_status":"0","recid":"3608","relation_version_is_last":true,"title":["セレンの電着に関する研究(第4報) : 濃硫酸浴(その2) : 醋酸,アルコール及び界面活性剤添加の影響について"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-07-25T15:18:46.492746+00:00"}