{"created":"2023-07-25T09:05:26.345350+00:00","id":3485,"links":{},"metadata":{"_buckets":{"deposit":"f30ddfad-0c0b-48d4-9639-0c0991a05218"},"_deposit":{"created_by":3,"id":"3485","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3485"},"status":"published"},"_oai":{"id":"oai:toyama.repo.nii.ac.jp:00003485","sets":["496:556:559:560:563"]},"author_link":["53310","53308","53309","53311"],"item_3_alternative_title_19":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"On the Electo-deposition of Metallic Selenium. (The 1st Report)"}]},"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1951-12","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"96","bibliographicPageStart":"91","bibliographicVolumeNumber":"3","bibliographic_titles":[{"bibliographic_title":"富山大学工学部紀要"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The electro-deposition of metallic Se from acid baths has been investigated for the purpose of application of the metal to the selenium rectifier. The influences of various electrolytic conditions to the states of deposited Se and the current efficiency were examined and discussed, and the suitable bath composition and the good electrolytic conditions were examined and discussed.\nThe requisites for the present purpose are an ample supply of Se cations, no hydrogen discharge and a definite temperature range.","subitem_description_type":"Abstract"},{"subitem_description":"セレン電荷の最も重要な目的はセレン整流器の製浩にある。若し電着によってこの目的を注することが出来れば整流器製法の操作が非常に簡素化され，而もセレン使用量を白由に加減出来る為セレンを無駄に消費する事が無く経済的であると同時に整流能，容量等の性能に対して著しい改善が期待される等の種々の利点が考えられるのである。\nセレン電着の主たる障碍はセレンの同質多形にある。セレンは周知の如く固態状態で四つの同素体を持つ。即ち無定形，α及びβ型の単斜晶系及び六方晶系のものである。無定形及び単斜晶系のものは電気の不導体であるが六方晶の所謂金属セレンは半導体であって整流体として使用出来るのは此物である。従って電着法に於ける重要な問題は電着物の形態と同時に如何にして金属セレンのみを析出せしめるかにある。セレンの電着については1829年Magnusが初めて実験を行い，続いでBerthelot, Miiller, Le Blanc等によって種々試みられたが析出物は非晶質であってこの問題を解決するに至っていない。又最近干平等及びHippel等によって金属セレンの電着が報告されているが，両者の得た結果には可成りの相異が認められる。著者は酸性溶液からの金属セレンの電着について種々検討しているが本報ではその基礎条件を得る目的で亜セレン酸酸性溶液を電解した際のセレンの析出状態，電流効率と種々の電解条件との関連について検討した結果を述べたい。猶前述のHippel等のものはNi基板について行ったものでその結果は著者等のものと多少の類似点が認められるが著者等の実験は之と全く別個に行われたものである。","subitem_description_type":"Abstract"}]},"item_3_description_40":{"attribute_name":"資源タイプ(DSpace)","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_3_description_6":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"富山大学工学部紀要，3(1)，1951-12, Page 91-96","subitem_description_type":"Other"}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"53310","nameIdentifierScheme":"WEKO"}],"names":[{"name":"IZAKI, Tosio"}]},{"nameIdentifiers":[{"nameIdentifier":"53311","nameIdentifierScheme":"WEKO"}],"names":[{"name":"YASUKAWA, Saburo"}]}]},"item_3_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.15099/00003479","subitem_identifier_reg_type":"JaLC"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"富山大学工学部"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00175872","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03871339","subitem_source_identifier_type":"ISSN"}]},"item_3_subject_22":{"attribute_name":"国立国会図書館分類","attribute_value_mlt":[{"subitem_subject":"ZM2","subitem_subject_scheme":"NDLC"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"位崎, 敏男"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"安川, 三郎"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-16"}],"displaytype":"detail","filename":"Kokiyo_3_01_Page091to096.pdf","filesize":[{"value":"8.6 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Kokiyo_3_01_Page091to096.pdf","url":"https://toyama.repo.nii.ac.jp/record/3485/files/Kokiyo_3_01_Page091to096.pdf"},"version_id":"15148ecc-2eb7-4c49-893b-05bfaa7c5c46"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"セレン","subitem_subject_scheme":"Other"},{"subitem_subject":"電着","subitem_subject_scheme":"Other"},{"subitem_subject":"電解浴","subitem_subject_scheme":"Other"},{"subitem_subject":"亜セレン酸酸性浴","subitem_subject_scheme":"Other"},{"subitem_subject":"電解条件","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"セレンの電着に関する研究(第一報)","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"セレンの電着に関する研究(第一報)"}]},"item_type_id":"3","owner":"3","path":["563"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-07-24"},"publish_date":"2012-07-24","publish_status":"0","recid":"3485","relation_version_is_last":true,"title":["セレンの電着に関する研究(第一報)"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-07-25T15:20:31.076461+00:00"}