{"created":"2023-07-25T09:05:25.238403+00:00","id":3459,"links":{},"metadata":{"_buckets":{"deposit":"d77befdd-3b3f-4521-afc3-eca451b819f9"},"_deposit":{"created_by":3,"id":"3459","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3459"},"status":"published"},"_oai":{"id":"oai:toyama.repo.nii.ac.jp:00003459","sets":["496:556:559:560:562"]},"author_link":["53280","53279"],"item_3_alternative_title_19":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Study on the dimethylglyoxime inner complex salt (The First Report) : On reaction with Potassium cyanide"}]},"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1950-12","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"51","bibliographicPageStart":"48","bibliographicVolumeNumber":"2","bibliographic_titles":[{"bibliographic_title":"富山大學工学部高岡工業專門学校紀要"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Nickel-dimethylglyoxime Complex salt is readily soluble in potassium cyanide, but the specific reaction and product in this case are unknown.\nNickel-dioxime salt is soluble in KCN Solution, forming Cyano Complex K_2 [Ni(CN)_4] and dimethylglyoxime-potassium salt. As evaporate the solution cyano complex salt is crystallized. By addition of alcohol white dimethylglyoxime-potassium is obtained from this filtrate,\nSince the specific reaction will be able to see that coordinated groups are substituted by CN' in alkali solution, and dimethylglyoxime free out from the masking action.\nSimilary copper, palladium, and Cobalt salts also dissolve in KCN solution, forming there Cyano complex and potassium dimethylglyoxime.","subitem_description_type":"Abstract"},{"subitem_description":"通常の赤色ニッケルヂオキシム錯塩がシアン化カリウム溶液に溶解する事は既に知られていたが，其の反応過程については今日迄明らかでなかった。筆者は此の特殊反応を追求するにあたり更にに銅，パラヂウム，コパルト等のヂオキシム塩についても同様の考察を試みたが，近着の雑誌に依りパラヂウムオキシム塩の此の特殊反応の機構について既に報告された事を知り全く同じ見解であったが敢えて此処に報告する。","subitem_description_type":"Abstract"}]},"item_3_description_40":{"attribute_name":"資源タイプ(DSpace)","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_3_description_6":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"富山大學工学部高岡工業專門学校紀要，2(1)，1950-12, Page 48-51","subitem_description_type":"Other"}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"53280","nameIdentifierScheme":"WEKO"}],"names":[{"name":"OI, Nobuiti"}]}]},"item_3_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.15099/00003453","subitem_identifier_reg_type":"JaLC"}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"富山大学工学部"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00175952","subitem_source_identifier_type":"NCID"}]},"item_3_subject_22":{"attribute_name":"国立国会図書館分類","attribute_value_mlt":[{"subitem_subject":"ZM2","subitem_subject_scheme":"NDLC"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"大井, 信一"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-16"}],"displaytype":"detail","filename":"Kokiyo_2_01_Page048to051.pdf","filesize":[{"value":"6.0 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Kokiyo_2_01_Page048to051.pdf","url":"https://toyama.repo.nii.ac.jp/record/3459/files/Kokiyo_2_01_Page048to051.pdf"},"version_id":"d652d8b5-a9d5-4527-a225-91363af606f5"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"ジメチルグリオキシム錯塩","subitem_subject_scheme":"Other"},{"subitem_subject":"シアン化カリ","subitem_subject_scheme":"Other"},{"subitem_subject":"赤色二ッケルジオキシム錯塩","subitem_subject_scheme":"Other"},{"subitem_subject":"ニッケル塩","subitem_subject_scheme":"Other"},{"subitem_subject":"銅塩","subitem_subject_scheme":"Other"},{"subitem_subject":"パラジウム塩","subitem_subject_scheme":"Other"},{"subitem_subject":"コバルト塩","subitem_subject_scheme":"Other"},{"subitem_subject":"隠蔽作用","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"ヂメチルグリオキシム錯塩に関する研究（第1報）シアン化カリとの作用について","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ヂメチルグリオキシム錯塩に関する研究（第1報）シアン化カリとの作用について"}]},"item_type_id":"3","owner":"3","path":["562"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-07-23"},"publish_date":"2012-07-23","publish_status":"0","recid":"3459","relation_version_is_last":true,"title":["ヂメチルグリオキシム錯塩に関する研究（第1報）シアン化カリとの作用について"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-07-25T15:20:46.377830+00:00"}