{"created":"2023-07-25T09:15:38.795677+00:00","id":15577,"links":{},"metadata":{"_buckets":{"deposit":"8f45a7b9-c1c8-4663-b901-5f3916821097"},"_deposit":{"created_by":17,"id":"15577","owners":[17],"pid":{"revision_id":0,"type":"depid","value":"15577"},"status":"published"},"_oai":{"id":"oai:toyama.repo.nii.ac.jp:00015577","sets":["439:467:468:469"]},"author_link":["167563","167564","167568","167566","167565"],"item_2_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-07","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"29","bibliographicPageEnd":"4327","bibliographicPageStart":"4324","bibliographicVolumeNumber":"56","bibliographic_titles":[{"bibliographic_title":"Tetrahedron Letters"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"An efficient synthesis of cyclohexane- and cyclopentane-1,3-dione-2-spirocyclopropanes from 1,3-cycloalkanediones using sulfonium salts was achieved. The reaction of 1,3-cycloalkanediones with (1-aryl-2-bromoethyl)dimethylsulfonium bromides and powdered K2CO3 in EtOAc provided the corresponding spirocyclopropanes in high yields. Furthermore, a one-pot synthesis of tetrahydroindol-4(5H)-one from 1,3-cyclohexanedione was achieved by using the present protocol and a sequential ring-opening cyclization of spirocyclopropane with a primary amine.","subitem_description_type":"Abstract"}]},"item_2_description_40":{"attribute_name":"資源タイプ(DSpace)","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_2_description_6":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"Tetrahedron Letters,  2015 Jul; 56(29): 4324-7","subitem_description_type":"Other"}]},"item_2_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1016/j.tetlet.2015.05.069","subitem_relation_type_select":"DOI"}}]},"item_2_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00861801","subitem_source_identifier_type":"NCID"}]},"item_2_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00404039","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"00404020","subitem_source_identifier_type":"ISSN"}]},"item_2_text_37":{"attribute_name":"編者等","attribute_value_mlt":[{"subitem_text_value":"Wiley"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Nambu, Hisanori"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fukumoto, Masahiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Hirota, Wataru"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ono, Naoki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yakura, Takayuki"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-01-30"}],"displaytype":"detail","filename":"TetrahedronLett_56(29)_4312to4315_nambu.pdf","filesize":[{"value":"123.9 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"TetrahedronLett_56(29)_4312to4315_nambu","url":"https://toyama.repo.nii.ac.jp/record/15577/files/TetrahedronLett_56(29)_4312to4315_nambu.pdf"},"version_id":"f2693fe4-ac47-44c8-999c-78b326ffb5d7"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Cyclopropane","subitem_subject_scheme":"Other"},{"subitem_subject":"1,3-Cyclohexanediones","subitem_subject_scheme":"Other"},{"subitem_subject":"Sulfonium salts","subitem_subject_scheme":"Other"},{"subitem_subject":"Indole","subitem_subject_scheme":"Other"},{"subitem_subject":"One-pot synthesis","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"An efficient synthesis of cycloalkane-1,3-dione-2-spirocyclopropanes from 1,3-cycloalkanediones using (1-aryl-2-bromoethyl)dimethylsulfonium bromides: application to a one-pot synthesis of tetrahydroindol-4(5H)-one","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"An efficient synthesis of cycloalkane-1,3-dione-2-spirocyclopropanes from 1,3-cycloalkanediones using (1-aryl-2-bromoethyl)dimethylsulfonium bromides: application to a one-pot synthesis of tetrahydroindol-4(5H)-one"}]},"item_type_id":"2","owner":"17","path":["469"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-01-30"},"publish_date":"2018-01-30","publish_status":"0","recid":"15577","relation_version_is_last":true,"title":["An efficient synthesis of cycloalkane-1,3-dione-2-spirocyclopropanes from 1,3-cycloalkanediones using (1-aryl-2-bromoethyl)dimethylsulfonium bromides: application to a one-pot synthesis of tetrahydroindol-4(5H)-one"],"weko_creator_id":"17","weko_shared_id":-1},"updated":"2023-07-25T14:34:13.560366+00:00"}