@article{oai:toyama.repo.nii.ac.jp:00015577, author = {Nambu, Hisanori and Fukumoto, Masahiro and Hirota, Wataru and Ono, Naoki and Yakura, Takayuki}, issue = {29}, journal = {Tetrahedron Letters}, month = {Jul}, note = {An efficient synthesis of cyclohexane- and cyclopentane-1,3-dione-2-spirocyclopropanes from 1,3-cycloalkanediones using sulfonium salts was achieved. The reaction of 1,3-cycloalkanediones with (1-aryl-2-bromoethyl)dimethylsulfonium bromides and powdered K2CO3 in EtOAc provided the corresponding spirocyclopropanes in high yields. Furthermore, a one-pot synthesis of tetrahydroindol-4(5H)-one from 1,3-cyclohexanedione was achieved by using the present protocol and a sequential ring-opening cyclization of spirocyclopropane with a primary amine., Article, Tetrahedron Letters, 2015 Jul; 56(29): 4324-7}, pages = {4324--4327}, title = {An efficient synthesis of cycloalkane-1,3-dione-2-spirocyclopropanes from 1,3-cycloalkanediones using (1-aryl-2-bromoethyl)dimethylsulfonium bromides: application to a one-pot synthesis of tetrahydroindol-4(5H)-one}, volume = {56}, year = {2015} }