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バレルスパッタリング法で調製したRu/α-Al₂0₃によるC0₂の水素化反応
https://doi.org/10.15099/00006509
https://doi.org/10.15099/00006509c8b08ea3-b812-44d1-8ad6-f6d4cb5c70bd
名前 / ファイル | ライセンス | アクション |
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annual_report28-1.pdf (3.0 MB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2009-05-29 | |||||
タイトル | ||||||
タイトル | バレルスパッタリング法で調製したRu/α-Al₂0₃によるC0₂の水素化反応 | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.15099/00006509 | |||||
ID登録タイプ | JaLC | |||||
著者 |
田口, 明
× 田口, 明× 谷澤, 昌昭× 赤丸, 悟士× 阿部, 孝之 |
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著者別名 | ||||||
姓名 | Taguchi, Akira | |||||
著者別名 | ||||||
姓名 | Tanizawa, Masaaki | |||||
著者別名 | ||||||
姓名 | Akamaru, Satoshi | |||||
著者別名 | ||||||
姓名 | Abe, Takayuki | |||||
その他(別言語等)のタイトル | ||||||
その他のタイトル | Study on the Hydrogenation of C0₂ over α-Al₂0₃ Supported Ru Nanoparticles Prepared by the Barrel-Sputtering Method | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Catalytic hydrogenation of CO₂over α-Al₂O₃ supported Ru nanoparticles (Ru/Al₂O₃)prepared by"barrel-sputtering" and conventional "wet impregnation" methods was investigated. Highly dispersed Ru nanoparticles were obtained by using the barrel-sputtering method. The mean particle diameter of Ru nanoparticles increased from ca. 5.5 to ca. 13.2 nm with an increase in the amount of Ru loaded. On the other hand, Ru particles were agglomerated when the impregnation method was used. Mean particle diameter of resultant Ru particles was 13.4 nm. Both catalysts showed selective methane production by hydrogenation of CO₂, and Ru/Al₂O₃ prepared by the barrel-sputtering method exhibited higher activity than that of Ru/Al₂O₃ prepared by the wet impregnation method. The turnover number (TON) of methane formation linearly decreased with an increase in the mean diameter of Ru nanoparticles. | |||||
書誌情報 |
富山大学水素同位体科学研究センター研究報告 = Annual Report of Hydrogen Isotope Research Center, University of Toyama 巻 28, p. 1-8, 発行日 2009-03 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1346-3675 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA11841872 | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 | ||||||
出版者 | 富山大学水素同位体科学研究センター | |||||
資源タイプ(DSpace) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article |