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Pd-Pt合金の水素同位体吸蔵-放出特性
https://doi.org/10.15099/00006436
https://doi.org/10.15099/00006436f2c809e9-b1d2-4715-aaad-55caa23a63aa
名前 / ファイル | ライセンス | アクション |
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annual_report17-8.pdf (483.0 kB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2007-10-03 | |||||
タイトル | ||||||
タイトル | Pd-Pt合金の水素同位体吸蔵-放出特性 | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.15099/00006436 | |||||
ID登録タイプ | JaLC | |||||
著者 |
安松, 拓洋
× 安松, 拓洋× 原, 正憲× 松山, 政夫× 渡辺, 国昭× SHU, W.M. |
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著者別名 | ||||||
姓名 | Yasumatsu, Takuyo | |||||
著者別名 | ||||||
姓名 | Hara, Masanori | |||||
著者別名 | ||||||
姓名 | Matsuyama, Masao | |||||
著者別名 | ||||||
姓名 | Watanabe, Kuniaki | |||||
その他(別言語等)のタイトル | ||||||
その他のタイトル | Absorption and Desorption of Hydrogen Isotopes by Palladium-Plati Alloys | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Absorption and desorption of hydrogen isotopes by Pd-Pt alloys are studied to find appropriate column materials for the self-developing gas chromatography around room temperature for hydrogen isotope separation. The equilibrium pressure of H2 and D2 increased with increasing Pt contents in the alloys in the range from 0 to 10 at%Pt, indicating that the free energy of hydrogen absorption and hydride formation decreased with Pt contents. It was found that the decrease in the free energy change is principally due to the decrease in the heat of absorption and hydride formation; the entropy change was kept almost constant irrespective of the alloy composition. On the other hand, the isotope effect evaluated from the ratio between the plateau pressures of H2 and D2 was not much dependent on the alloy composition, indicating that any alloy investigated will be applicable as a separation column, depending on operation conditions of the self-developing gas chromatography. | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 富山大学水素同位体機能研究センター研究報告 17, 85-96.(1997) | |||||
書誌情報 |
富山大学水素同位体機能研究センター研究報告 巻 17, p. 85-96, 発行日 1997 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0916-8486 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN10443060 | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 | ||||||
出版者 | 富山大学水素同位体機能研究センター | |||||
資源タイプ(DSpace) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article |