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The Ⅲa transition metals used were Sc, Y, and Ho as a lanthanide element. The hydrogenated alloys were examined for absorption and desorption behavior of hydrogen, internally hydrided structure, identification of hydrides, changes in hardness of the alloys, and effects of additive elements, such as Ag, Al, Cd, Li, Pb, Sn, and Zn, on the internal hydriding of Mg-5Y alloy. Results obtained are as follows: 1. The Mg-alloys containing Ⅲa transition metals could absorb much more amounts of hydrogen than magnesium-itself and form hydrides of the metals in the matrix. 2. These hydrides were identified as ScH2, YH2, and HoH2, respectively, and formed on the specific crystallographic planes in the magnesium matrix. They were so stable that they did not decompose by heat treatment in a vacuum at the hydrogenating temperature. 3. The Mg-Sc alloys were hardened by internal hydriding, while softening took place in the Mg-Y and Mg-Ho alloys by hydriding. This discrepancy might be attributed to the difference in compromise between the decrease of solid solution hardening and the increase of dispersion hardening by hydriding. However, because of dispersed stable hydrides, all the internally hydrided alloys were expected to have an appreciable strength at high temperatures. 4. Investigating the effect of each additive element added by 2-3 at% on the internal hydriding of Mg-5 mass% (1.5 at%) Y alloy, it was found that the hydriding was almost arrested by the addition of Ag, Al, Cd, Pb, and Sn, respectively, and arrested to a certain degree by the addition of Zn, while it was little affected by the addition of Li.", "subitem_description_type": "Abstract"}]}, "item_3_description_40": {"attribute_name": "資源タイプ(DSpace)", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_3_full_name_3": {"attribute_name": "著者別名", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "59754", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "Matsuyama, Masao"}]}, {"nameIdentifiers": [{"nameIdentifier": "59755", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "Watanabe, Kuniaki"}]}, {"nameIdentifiers": [{"nameIdentifier": "59756", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "Morozumi, Shotaro"}]}, {"nameIdentifiers": [{"nameIdentifier": "59757", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "Iijima, Masayuki"}]}]}, "item_3_identifier_registration": {"attribute_name": "ID登録", "attribute_value_mlt": [{"subitem_identifier_reg_text": "10.15099/00006399", "subitem_identifier_reg_type": "JaLC"}]}, "item_3_publisher_33": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "富山大学水素同位体機能研究センター"}]}, "item_3_source_id_10": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AN10443060", "subitem_source_identifier_type": "NCID"}]}, "item_3_source_id_8": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0916-8486", "subitem_source_identifier_type": "ISSN"}]}, "item_3_version_type_16": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "松山, 政夫"}], "nameIdentifiers": [{"nameIdentifier": "59750", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "渡辺, 国昭"}], "nameIdentifiers": [{"nameIdentifier": "59751", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "諸住, 正太郎"}], "nameIdentifiers": [{"nameIdentifier": "59752", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "飯島, 正幸"}], "nameIdentifiers": [{"nameIdentifier": "59753", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2016-02-17"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "annual_report13-3.pdf", "filesize": [{"value": "885.8 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 885800.0, "url": {"label": "annual_report13-3.pdf", "url": "https://toyama.repo.nii.ac.jp/record/6405/files/annual_report13-3.pdf"}, "version_id": "8991834e-7c85-4e1e-9221-47842bb93d84"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Mg-Ⅲa族遷移金属合金の内部水素化", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Mg-Ⅲa族遷移金属合金の内部水素化"}]}, "item_type_id": "3", "owner": "3", "path": ["792"], "permalink_uri": "https://doi.org/10.15099/00006399", "pubdate": {"attribute_name": "公開日", "attribute_value": "2007-10-03"}, "publish_date": "2007-10-03", "publish_status": "0", "recid": "6405", "relation": {}, "relation_version_is_last": true, "title": ["Mg-Ⅲa族遷移金属合金の内部水素化"], "weko_shared_id": -1}
Mg-Ⅲa族遷移金属合金の内部水素化
https://doi.org/10.15099/00006399
https://doi.org/10.15099/00006399af19f655-7ecc-4b36-961b-0449314d55ae
名前 / ファイル | ライセンス | アクション |
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annual_report13-3.pdf (885.8 kB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2007-10-03 | |||||
タイトル | ||||||
タイトル | Mg-Ⅲa族遷移金属合金の内部水素化 | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.15099/00006399 | |||||
ID登録タイプ | JaLC | |||||
著者 |
松山, 政夫
× 松山, 政夫× 渡辺, 国昭× 諸住, 正太郎× 飯島, 正幸 |
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著者別名 | ||||||
姓名 | Matsuyama, Masao | |||||
著者別名 | ||||||
姓名 | Watanabe, Kuniaki | |||||
著者別名 | ||||||
姓名 | Morozumi, Shotaro | |||||
著者別名 | ||||||
姓名 | Iijima, Masayuki | |||||
その他(別言語等)のタイトル | ||||||
その他のタイトル | Internal Hydriding of Mg-?a Transition Metal Alloys | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Mg-Ⅲa transition metal alloys were hydrogenated at 773K (500℃) under 570 torr of hydrogen. The Ⅲa transition metals used were Sc, Y, and Ho as a lanthanide element. The hydrogenated alloys were examined for absorption and desorption behavior of hydrogen, internally hydrided structure, identification of hydrides, changes in hardness of the alloys, and effects of additive elements, such as Ag, Al, Cd, Li, Pb, Sn, and Zn, on the internal hydriding of Mg-5Y alloy. Results obtained are as follows: 1. The Mg-alloys containing Ⅲa transition metals could absorb much more amounts of hydrogen than magnesium-itself and form hydrides of the metals in the matrix. 2. These hydrides were identified as ScH2, YH2, and HoH2, respectively, and formed on the specific crystallographic planes in the magnesium matrix. They were so stable that they did not decompose by heat treatment in a vacuum at the hydrogenating temperature. 3. The Mg-Sc alloys were hardened by internal hydriding, while softening took place in the Mg-Y and Mg-Ho alloys by hydriding. This discrepancy might be attributed to the difference in compromise between the decrease of solid solution hardening and the increase of dispersion hardening by hydriding. However, because of dispersed stable hydrides, all the internally hydrided alloys were expected to have an appreciable strength at high temperatures. 4. Investigating the effect of each additive element added by 2-3 at% on the internal hydriding of Mg-5 mass% (1.5 at%) Y alloy, it was found that the hydriding was almost arrested by the addition of Ag, Al, Cd, Pb, and Sn, respectively, and arrested to a certain degree by the addition of Zn, while it was little affected by the addition of Li. | |||||
書誌情報 |
富山大学水素同位体機能研究センター研究報告 巻 13, p. 31-50, 発行日 1993 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0916-8486 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN10443060 | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 | ||||||
出版者 | 富山大学水素同位体機能研究センター | |||||
資源タイプ(DSpace) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article |