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One kind of amphiphilic polyamide has been synthesized\nand spread on the pure water. The surface pressure waskept constant at values between 20\nand 30mN/m at 25℃ and multilayers were tranferred onto ITO coated glass substrates by the\nvertical dipping method using our own-made moving wall type LB trough. Two kinds of\nimidization methods were tried, i.e. (1)heat-treatment \u0026 (2)polimerization in a solution of anhydrous\nacetic acid, pyrimidine and benzene in the ratio of 1:1:3 (volume). Capacitance versus\nvoltage and optical transmittance versus applied voltage characteristics of nematic liquid crystal\ncells showed hysteretic behavior, i.e. memory effect, for the cases of low temperature heat treated\npolyiamide LB layers. On the other hand, no hysteretic behavior was observed for the cases of\nhigh temperature heat-treated or the solution-treated LB layers. 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液晶配向ラングミュア・プロジェクト(LB)膜の作製
https://doi.org/10.15099/00004436
https://doi.org/10.15099/00004436539d817f-1aa9-4e3d-8f2b-46dfd2d07f82
名前 / ファイル | ライセンス | アクション |
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Kokiyo_43_01_Page045to050.pdf (2.1 MB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2012-10-11 | |||||
タイトル | ||||||
タイトル | 液晶配向ラングミュア・プロジェクト(LB)膜の作製 | |||||
言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 液晶配向ラングミュア・プロジェクト(LB)膜 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Langmuir- Blodgett膜 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | LB膜 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 液晶セル | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | ポリアミド酸LB膜 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | ヒステリシス | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | メモリー特性 | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.15099/00004436 | |||||
ID登録タイプ | JaLC | |||||
著者 |
尾山, 実
× 尾山, 実× 柴田, 幹× 女川, 博義× 宮下, 和雄 |
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著者別名 | ||||||
姓名 | Oyama, Minoru | |||||
著者別名 | ||||||
姓名 | Shibata, Miki | |||||
著者別名 | ||||||
姓名 | Onnagawa, Hiroyoshi | |||||
著者別名 | ||||||
姓名 | Miyashita, Kazuo | |||||
その他(別言語等)のタイトル | ||||||
その他のタイトル | Preparation of Polyimide Langmuir Blodgett Films for Use in Aligning Liquid Crystal Molecules | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Experimental conditions to prepare good Langmuir-Blodgett (LB) films for aligning liquid crystal molecules have been i00nvest0igated. One kind of amphiphilic polyamide has been synthesized and spread on the pure water. The surface pressure waskept constant at values between 20 and 30mN/m at 25℃ and multilayers were tranferred onto ITO coated glass substrates by the vertical dipping method using our own-made moving wall type LB trough. Two kinds of imidization methods were tried, i.e. (1)heat-treatment & (2)polimerization in a solution of anhydrous acetic acid, pyrimidine and benzene in the ratio of 1:1:3 (volume). Capacitance versus voltage and optical transmittance versus applied voltage characteristics of nematic liquid crystal cells showed hysteretic behavior, i.e. memory effect, for the cases of low temperature heat treated polyiamide LB layers. On the other hand, no hysteretic behavior was observed for the cases of high temperature heat-treated or the solution-treated LB layers. Especially, for the cells with the solution treated LB aligning layers, uniform and defect-free alignment was obtained.0 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | 液晶分子配列用の高品質ラングミュアーブロジェット(LB)膜作製法について研究した。 1種のポリアミド酸を合成し純水上に展開した。 自作のムービングウォール型LB 膜作製トラフを用い,25℃において表面張力を20~30mN/mの間で一定に保って,ITO 基板を垂直に上げ下げして多重層を堆積させた。 イミド化法として(1)熱処理と(2)無水酢酸:ピリジン:べンゼン体積比 1:1:3 の混合溶液処理法の2つの方法を試した。 低温熱処理法によるLB膜による液晶セルの場合には静電容量電圧特性,光透過度一電圧特性にヒステリシス,すなわち,メモリー特性が現れた。 一方,高温熱処理または溶液処理したLB膜の場合にはヒステリシスは現れなかった。 特に,溶液処理したLB膜を用いた液晶セルでは液晶分子が一様配向した配向欠陥の無いものが得られた。 |
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引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 富山大学工学部紀要,43, Page 45-50 | |||||
書誌情報 |
富山大学工学部紀要 巻 43, p. 45-50, 発行日 1992-03 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 03871339 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00175872 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
国立国会図書館分類 | ||||||
主題Scheme | NDLC | |||||
主題 | ZM2 | |||||
出版者 | ||||||
出版者 | 富山大学工学部 | |||||
資源タイプ(DSpace) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article |