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Catalyst Activity and Selectivity for Liquid-Phase Oxidation of Sodium Sulfide catalyzed by Various Materials
https://doi.org/10.15099/00004246
https://doi.org/10.15099/000042466ac7c9d2-0ecd-4290-8a15-84c2c884b62a
名前 / ファイル | ライセンス | アクション |
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Kokiyo_31_01_Page028to032.pdf (999.4 kB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2012-10-03 | |||||
タイトル | ||||||
タイトル | Catalyst Activity and Selectivity for Liquid-Phase Oxidation of Sodium Sulfide catalyzed by Various Materials | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 触媒 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 硫化ナトリウム | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 液相酸化反応 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 触媒活性 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 選択性 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Liquid-Phase Oxidation of Sodium Sulfide | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Catalyst Activity | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Selectivity | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Oxidation products | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Metal sulfates | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.15099/00004246 | |||||
ID登録タイプ | JaLC | |||||
著者 |
坂井, 徹
× 坂井, 徹× 大井, 信一 |
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著者別名 | ||||||
姓名 | SAKAI, Tohru | |||||
著者別名 | ||||||
姓名 | OHI, Nobuichi | |||||
その他(別言語等)のタイトル | ||||||
その他のタイトル | 種々の触媒を用いる硫化ナトリウムの液相酸化反応の触媒活性および選択性 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The liquid-phase oxidation of sodium sulfide catalyzed by various materials such as 4 sulfur dyes, 6 vat dyes, CuSO_4, MnSO_4, CoSO_4, FeSO_4, pyrocatechol, and sulfate lignin have been studied, and catalyst activity and selectivity for this oxidation of the employed catalysts have been investigated. Measurement of time-course of concentration of liquid compounds was carried out with a stirred vessel under aeration, while that of a absorption rate of oxygen was performed in a batchwise operation. Oxidation products were Na_2S_2, Na_2SO_3, and mainly Na_2S_20_3. At first, Na_2S_2, Na_2SO_3 and Na_2S_20_3 were formed by oxidation of Na_2S simultaneously, and Na_2S_20_3 was also formed by the reaction of Na_2S_2 with Na_2S0_3 subsequently. In general, catalyst activity of sulfur dyes was higher than that of vat dyes, and that of metal sulfates such as MnSO_4, CuSO_4, and CoSO_4 was particularly high. Metal sulfates had a high selectivity for the formation of Na_2S_20_3. A presumption of reaction mechanism was somewhat described. |
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引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 富山大学工学部紀要,31 | |||||
書誌情報 |
富山大学工学部紀要 巻 31, p. 28-32, 発行日 1980-03 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 03871339 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00175872 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
国立国会図書館分類 | ||||||
主題Scheme | NDLC | |||||
主題 | ZM2 | |||||
出版者 | ||||||
出版者 | 富山大学工学部 | |||||
資源タイプ(DSpace) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article |