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アルミニウム粒と四塩化炭素との反応の芳香族カルボン酸塩添加による阻害作用
https://doi.org/10.15099/00003942
https://doi.org/10.15099/000039421957f514-2c2a-4553-b5d0-a131f494805c
名前 / ファイル | ライセンス | アクション |
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Kokiyo_17_01_Page032to038.pdf (5.9 MB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2012-09-24 | |||||
タイトル | ||||||
タイトル | アルミニウム粒と四塩化炭素との反応の芳香族カルボン酸塩添加による阻害作用 | |||||
言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | アルミニウム粒 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 四塩化炭素 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 芳香族カルボン酸塩添加 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 阻害作用 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 比導電率 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 臨界モル濃度 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | イオン化能 | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.15099/00003942 | |||||
ID登録タイプ | JaLC | |||||
著者 |
浅岡, 忠知
× 浅岡, 忠知× 島崎, 長一郎× 豊田, 絢一郎× 谷口, 美紀生 |
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著者別名 | ||||||
姓名 | ASAOKA, Tadatomo | |||||
著者別名 | ||||||
姓名 | SHIMASAKI, Choichiro | |||||
著者別名 | ||||||
姓名 | TOYOTA, Kenitiro | |||||
著者別名 | ||||||
姓名 | TANIGUTI, Mikio | |||||
その他(別言語等)のタイトル | ||||||
その他のタイトル | Retarding Action of Various Metallic Salts of some Aromatic Carboxylic Acid on the Reaction between Aluminum Particles and Carbon Tetrachloride | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | In the preceding paper it was shown that the reaction between aluminum particles and carbon tetrachloride was ionic considering the relation of the induction period with each metallic salt versus their electric conductivity. Now the simi1ar studies using various metallic salts of some aromatic carboxylic acid which may ionize in the organic solvent are carried out. The result obtained is as follows: (1) In the influence of water of crystallization on the induction period the linear relation was not found between the critical concentration of the induction period and the water content, as was suggested by M. Stern, and it is explained that its discrepancy came from the difference of each temperature at which water was liberated. (2) For the 6 sorts of aromatic carboxylic acids the order of the prolonged effect is as follows: salicylic -> methylenedisalicylic -> alkylsalicylates > benzoic-. (3) In various metallic salts of aromatic carboxylic acid, metallic salicylates or metallic methylenedisalicylates gave the negative effects compared with respective acid, while metallic benzoates gave the positive effects. (4) Since various metallic salts of aromatic carboxylic acid have respectively specified ionizing abi1ity in the organic solvent, some relation of the critical concentration to the induction period versus the specific coductivity is obtained. |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | 著者達の研究室では従来Al粒とCCl_4との反応について,各種阻害剤の添加効果の研究を行なって来ている。 これと関連して前報においては有機溶媒中で電離性のあるジイソプロピルサリチル酸塩(本稿中ではDips塩と略記する)の添加効果について報告し,この反応系の阻害作用は導電率と密接な関係があることを認め,これらの反応がある程度イオン的に進むことを指摘した。 本報ではこれに引続いて芳香族カルボン酸として安息香酸,サリチル酸およびメチレンジサリチル酸(本稿中ではM.D.S.Aと略記する)の各種金属塩の添加による阻害作用について報告する。 |
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引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 富山大学工学部紀要,17(1/2) | |||||
書誌情報 |
富山大学工学部紀要 巻 17, 号 1/2, p. 32-38, 発行日 1966-03 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 03871339 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00175872 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
国立国会図書館分類 | ||||||
主題Scheme | NDLC | |||||
主題 | ZM2 | |||||
出版者 | ||||||
出版者 | 富山大学工学部 | |||||
資源タイプ(DSpace) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article |