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アルミニウム粒と四塩化炭素との反応のメルカプタン類添加による阻害作用ならびに溶媒効果
https://doi.org/10.15099/00003878
https://doi.org/10.15099/0000387810ed6ac0-9e86-433a-8767-b28d7fc9dca3
名前 / ファイル | ライセンス | アクション |
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Kokiyo_15_01_Page053to058.pdf (7.1 MB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2012-09-20 | |||||
タイトル | ||||||
タイトル | アルミニウム粒と四塩化炭素との反応のメルカプタン類添加による阻害作用ならびに溶媒効果 | |||||
言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | アルミニウム粒 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 四塩化炭素 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | メルカプタン類添加による阻害作用 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 溶媒効果 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | リグロイン | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 誘導期 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 誘導期におよぼす影響 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 溶媒効果 | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.15099/00003878 | |||||
ID登録タイプ | JaLC | |||||
著者 |
浅岡, 忠知
× 浅岡, 忠知× 作道, 栄一× 島崎, 長一郎× 武部, 幹夫 |
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著者別名 | ||||||
姓名 | ASAOKA, Tadatomo | |||||
著者別名 | ||||||
姓名 | TSUKURIMITI, Eiiti | |||||
著者別名 | ||||||
姓名 | SIMASAKI, Choitiro | |||||
著者別名 | ||||||
姓名 | TAKEBE, Mikio | |||||
その他(別言語等)のタイトル | ||||||
その他のタイトル | Retarding Action of Various Mercaptanes on the Reaction between Aluminum Particles and Carbon Tetrachloride, and Solvent Effects for this reaction | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Retarding action of many sorts of inhibitors on the reaction between aluminum particles and carbon tetrachloride was reported in the previous many papers. Now, analogous studies with mercaptanes as inhibitor are carried out and further more solvent effects of ligroins are checked. The outline of results may be summarized in the following: (1) N-alkyl-, sec-(iso-)alkyl mercaptanes prolonged the induction period, but tert-alkyl mercaptanes did not affect that period irrespective their carbon number. (2) ln the mercaptanes having lower alkyl, the order of the prolonged effect is shown as follows: n-<sec-(iso)<tert-. (3) It is recognized that aromatic mercaptanes are more valid for prolonging the induction period than aliphatic mercaptanes. (4) Since mercaptanes is weaker agents for coordinating with produced AlCl_3 and less reactive for aluminum particles than corresponding alcohols, the former is inferior to the latter for prolonging the induction period. (5) ln the case of pretreatment of aluminum particles, benzyl mercaptane is inferior to tert-butyl, but regarding to washing effect, if any benzyl mercaptane is sorped (chemical sorpticn) on the surface of aluminum particles, this film is very powerful. (6) In solvent effect, the induction period is shortened with a narrow range having the small quantity, but is prolonged with the quantity beyond that range. |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | アルミニウム粒と四塩化炭素の反応について,各種の阻害剤の添加効果の研究に対しては従来浅岡らが多数の報告を行って来ている。 本報ではこれらに関連して,メルカプタン類添加の場合と,溶媒としてリグロインを添加した場合の誘導期におよぼす影響について行ったものである。 |
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引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 富山大学工学部紀要,15(1/2) | |||||
書誌情報 |
富山大学工学部紀要 巻 15, 号 1/2, p. 53-58, 発行日 1964-03 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 03871339 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00175872 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
国立国会図書館分類 | ||||||
主題Scheme | NDLC | |||||
主題 | ZM2 | |||||
出版者 | ||||||
出版者 | 富山大学工学部 | |||||
資源タイプ(DSpace) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article |