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62(P-39) 矢毒ガエルアルカロイド223A,205B,207I,223Iの全合成(ポスター発表の部)
http://hdl.handle.net/10110/00018237
http://hdl.handle.net/10110/00018237e55f65bc-3bf1-4b50-a473-1628e1345aa0
名前 / ファイル | ライセンス | アクション |
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SympoChemNaturalProducts_45_365to370_Toyooka (484.1 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2018-03-01 | |||||
タイトル | ||||||
タイトル | 62(P-39) 矢毒ガエルアルカロイド223A,205B,207I,223Iの全合成(ポスター発表の部) | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | 62(P-39) Total Synthesis of Dart-Poison Frog Alkaloids 223A, 205B, 207I, 223I | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
豊岡, 尚樹
× 豊岡, 尚樹× 福留, 彩子× 根本, 英雄× 篠田, 裕之× Daly, John W.× Spande, Thomas F.× Garraffo, H. Martin× Kaneko, Tetsuo× 川崎, 正志 |
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著者別名 | ||||||
姓名 | Toyooka, Naoki | |||||
著者別名 | ||||||
姓名 | Fukutome, Ayako | |||||
著者別名 | ||||||
姓名 | Nemoto, Hideo | |||||
著者別名 | ||||||
姓名 | Shinoda, Hiroyuki | |||||
著者別名 | ||||||
姓名 | Daly, John W. | |||||
著者別名 | ||||||
姓名 | Spande, Thomas F. | |||||
著者別名 | ||||||
姓名 | Garraffo, H. Martin | |||||
著者別名 | ||||||
姓名 | 金子, 哲夫 | |||||
著者別名 | ||||||
姓名 | Kawasaki, Masasi | |||||
その他(別言語等)のタイトル | ||||||
その他のタイトル | 62(P-39) Total Synthesis of Dart-Poison Frog Alkaloids 223A, 205B, 207I, 223I | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | A remarkably diverse array of biologically active alkaloids, for example, blockers of neuromuscular-type, ganglionic-type, and nicotinic receptor channels, occurs in amphibian skin, and over 500 alkaloids have been isolated to date. The structural diversity and pharmacological activity associated with these alkaloids have stimulated research in numerous synthetic groups. Among them, we achieved the first synthesis of the alkaloids 223A has been accomplished, the proposed structure has been revised, and the relative stereostructure of natural 223A was determined. We have demonstrated the first enantioselective total synthesis of the antipode of structurally unique alkaloid 205B, and the absolute stereochemistry of natural 205B has been determined to be 2aR, 5aR, 6S, 8S, 8aR. Furthermore, we achieved the chiral synthesis of quinolizidine 207I and its absolute stereochemistry was determined to be 1S, 4S, 10S by the GC-coinjection analysis of racemic compound and natural product. Finally, we also achieved the synthesis of both stereoisomers for the alkaloid 223I, and the determination of the ralative stereochemistry of natural 223I using GC-coinjection analysis of these isomers and natural product is now under investigations. | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 天然有機化合物討論会講演要旨集 45, 365-370.(2003) | |||||
書誌情報 |
天然有機化合物討論会講演要旨集 en : Symposium on the Chemistry of Natural Products, symposium papers 巻 45, p. 365-370, 発行日 2003-09-01 |
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書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00154136 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.24496/tennenyuki.45.0_365 | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
論文ID(NAID) | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | NAID | |||||
関連識別子 | 110006682321 | |||||
出版者 | ||||||
出版者 | 天然有機化合物討論会 | |||||
資源タイプ(DSpace) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article |